2.1.5 - Redox Flashcards
(48 cards)
Define oxidation number
Based on a set of rules that apply to atoms. It can be thought of as number of electrons involved in bonding to a different element.
How can you use oxidation numbers?
Helps when writing formulae and in balancing electrons as a check that all electrons have been accounted for.
What is the rule for elements?
The oxidation is always zero for elements!
What is the oxidation number of H2?
0
What is the oxidation number of S8?
0
What is the oxidation number of Na?
0
What is the rule for compounds and ions?
Each atom in a compound has an oxidation number. An oxidation number has a sign which is placed before the number.
Give two examples of compounds with the oxidation number -2
- H2O
- CaO
Give two examples of compounds with the oxidation number +1
- NH3
- H2S
Give an example of a compound with the oxidation number -1
- HF
Give two examples of compounds with the oxidation number +1
- NaCl
- K2O
Give two examples of compounds with the oxidation number +2
- MgCl2
- CaO
Give three examples of compounds with the oxidation number -1
- HCl
- KBr
- CaI2
Give two examples of ‘H in Hydrides’ with the oxidation number -1
- NaH
- CaH2
Give an example of ‘O in Peroxides’ with the oxidation number +1
H2O2
Give an example of ‘O bonded to F’ with the oxidation number +2
F2O
Define the oxidation number in an ion.
The oxidation number of an ion is numerically the same as the ionic charge but the sign comes before the number.
The sum of the oxidation numbers = total charge
How do you work out the oxidation number for Sulfur in H2SO4?
- Step 1:
- Assign any oxidation numbers from the rules
- H2SO4 (Total hydrogens +1x2=+2) and (Total oxygens -2x4=-8)
- Step 2:
- What is the sum of the oxidation numbers?
- Sum of oxidation numbers = total charge = 0
- Step 3:
- Work out the unknown oxidation numbers
- Sum of oxidation numbers = (+2) + (x) + (-8) = 0
- (-6) + (x) = 0
- x = 6
Redox in terms of electrons
Oxidation
Is
Loss
Reduction
Is
Gain
Redox Reactions of Acids
Acids produce salts in neutralisation reactions. Dilute acids also undergo redox reactions with some metals to produce salts and hydrogen gas.
What are polyatomic ions?
Polyatomic ions contain oxygen for example: NO2(-) (-ite) and NO3(-) (-ate). Although still in common usage using -ite and -ate in naming this is old fashioned, today we use oxidation numbers shown as Roman Numerals.
Polyatomic ion NO2(-)
Ion - NO2(-)
Common Name - Nitrite
Oxidation Number of Nitrogen - +3
Modern Name - Nitrate (III)
Polyatomic ion NO3(-)
Ion - NO3(-)
Common Name - Nitrate
Oxidation Number of Nitrogen - +5
Modern Name - Nitrate (V)
What does redox stand for?
Redox stands for reduction-oxidation, a type of chemical reaction where oxidation and reduction processes occur simultaneously.