2.1.5 Redox Flashcards
Oxidation number of elements is always
Zero
O oxidation number
-2 e.g in CaO, H2O
H oxidation number
+1 e.g in NH3, H2S
F oxidation number
-1 (e.g HF)
Na+, K+ oxidation number
+1
Mg2+, Ca2+ oxidation number
+2
Cl-, Br-, I- oxidation nunber
-1
What is the oxidation number of H in metal hydrides (e.g NaH, CaH2)
-1
What is the oxidation number of O in peroxides (H2O2)
-1
Oxidation number of O bonded to F (F2O)
+2
Sum of oxidation numbers is equivalent to
The total charge
Worked example using formulae using oxidation numbers
E.g oxidation nunber of N in NO3-
-> O = -2 so O3 is -6
Total charge = -1
-6 - - 1 = N = 5
The roman numeral shows the […] of an element e.g for iron (II)
oxidation state
-> iron (II) = oxidation number +2 = Fe2+
Nitrate (III) is NO2-. What is the oxidation number of N
+3
Sulfate formula
SO42-
Oxidation is terms of oxygen
The addition of oxygen
Reduction in the case of oxygen
Removal of oxygen
OILRIG (in terms of electrons)
Oxidation is loss, reduction is gain
Redox in terms of oxidation number
Reduction = a decrease in oxidation number
Oxidation = an increase in oxidation number
Reaction of Zinc with HCl
Zn + 2HCl -> ZnCl2 + H2
-> Zn oxidises as its number increases by 2, while H reduces.
What is a disproportionate reaction
One where the same element is both oxidised and reduced