2.1.3 Amount of substance Flashcards
Define (one) mole
Amount of substance that contains 6.02x1023 particles
Avogadro constant
The number of particles per mole, 6.02x1023 mol-1
Molar mass
Mass per mole of a substance (units= g mol-1)
Molar gas volume
Gas volume per mole
(units= dm3 mol-1)
The volume occupied by one mole of any gas (24 dm³ or 24000 cm³ at room temperature and pressure).
Empirical formula
Simplest whole number ratio of atoms of each element
present in a compound
Molecular formula
Number and type of
atoms of each element in a molecule
Anhydrous
Contains no water of crytsallisation
Hydrated
The solid crystals contain water of crystallisation
Water of crystallisation
Water that is chemically bonded into a crystal structure
Recall calculation involving mass
n = m / Mr
Recall calculation involving gas volume
Volume = n × molar volume
Recall calculation involving solution volume and concentration
n = conc. x volume
Recall Ideal gas equation
pV=nRT
p=pressure (Pa)
V=volume (m3)
n=No. of mol
R=gas constant
(8.31) (JK-1 mol-1)
T=temperature (K) (+273)
Pressure at room temperature
1 atmosphere = 101 kPa
1kPa = 1,000 Pa
1 bar = 100,000 Pa
Room temperature
20 degrees celsius = 293 K
Standard temperature
25 degrees celsius = 298 K
Recall equation for percentage yield
Yield (%) =
Yield / Maximum theoretical yield x100
Atom economy
Tells us what percentage of the mass of the reactant atoms ends up in the desired product
Recall equation for atom economy
Atom economy (%) =
Molecular mass of desired product / Sum of molecular masses of all reactants x100
(large numbers in chemical equation count for atom economy)
Benefits for sustainability of chemical processes with a high atom economy
-reactions with high atom economy are more sustainable than those with low atom economy because less of the mass of reactants ends up in the waste products
-waste product of 1 reaction may be used by a chemical producer as starting material for a different reaction >increases overall sustainability
-reactions with large input of energy are less sustainable