2.1.3 Amount Of Substance Flashcards
Mole
Amount of substance in gramd that has the same number of particles as there are atoms in 12 grams of carbon-12
Relative atomic mass
Average mass of one atom compared to 1/12th mass of one atom of carbon-12
Molar mass
Mass in grams of one mole of a substance and is given in units g/mol
Molar gas volume
Volume one mole of gas at given temperature and pressure, all gases have this volume
Room temperature and pressure
1atm
25 degrees
Molar gas volume at RTP
24 dm3
24,000 cm3
Avogadros constant
6.02 x 10^23 atoms in 12 grams of carbon-12
calculate moles
Mass divided by mr
Empirical formulae
Simplist whole number ratio of atoms of each element in the compound
Method to work out empirical formula
- Divide each mass by atomic mass of element
- Divide each answer from step one by lowest number in that stage
- Multiply to adjust ratio to whole numbers
Molecular formula
Actual number of atoms of each element in the compound
Hydrated salt practical
Weigh empty crucible and lid
Add hydrated copper sulfate and weigh again
Heat using Bunsen burner
Allow to cool
Weigh crucible and contents again
Heat crucible again and reweigh until you reach a constant mass
Why must crucible be dry at the start of experiment
As a wet crucible would give an inaccurate result
Cause mass loss to be too large as water would be lost when heating
Two assumptions made in copper sulfate practical
- All water is evaporated
2. No further decomposition occurs
Calculating moles using conc
n= conc x volume x 10^-3
Unit is dm^3
Making a standard solution
Weigh sample bottle with mass of solid Transfer to beaker and reweigh bottle Record mass difference Add 100 cm3 of water and use a glass rod to dissolve solid Heat gently to help dissolve Pour into 250cm3 flask using a funnel Rinse beaker and funnel and add washings into flask Fill to mark Invert several times
Diluting a solution
Pipette 25cm3 of original solution into 250cm3 volumetric flask
Make up to mark with distilled water using dropping pipette
Invert several times
Calculating dilutions
New conc = old conc x old vol/new vol
Safety hazards
Irritant- dilute acids and alkalis, wear glasses
Corrosive-stronger acid and alkalis wear goggles
Flammable-keep away from naked flames
Toxic-wear gloves, avoid skin contact, wash hands after use
Oxidising- keep away from flammable or easily oxidised materials
ideal gas equation
PV=nRT
Units for ideal gas equation
Pressure= pascals Volume= m^3 Temp= K n=moles R = 8.314 J/K/mol
Potential errors using a gas syringe
Gas escapes before bung inserted
Syringe sticks
Some gases are soluble in water so true amount isn’t measured
Reacting volumes of gas
Equal volumes of gas measured under same conditions of temperature and pressure contain equal number of moles
Number of particles calculation
mol x avogadros constant