2.1 energetics Flashcards
Exothermic reactions
Products have less energy than the reactants, sum of reactants bonds is less
Enthalpy change
Amount of heat energy transferred during a change in a system, at a constant pressure
Endothermic reactions
Products have more energy than reactants, sum of reactants bonds is more than sum of products bonds
Enthalpy of formation
Enthalpy change when one mole of a compound is formed from its constituent elements under standard conditions, all reactants and products in their standard states
Enthalpy of combustion
The enthalpy change when one mole of a substance is completely burned in oxygen under standard conditions, all reactants and products in their standard states
Experiments
Wash, dry, initial temperature, add solid, stir, final temperature
Errors in experiments
Hard to measure temperature of solids, slow reactions cool, heat loss, incomplete dissolving, assumed density and shc
Hess’s law
The total enthalpy change for a reaction is independent of the route taken by the chemical change
Working out enthalpy of formation
Products minus reactants
Working out enthalpy of combustion
Reactants minus products
Mean bond enthalpy
Enthalpy needed to break the covalent bonds in gaseous atoms, averaged over a range of compounds