2.1. Chemical equations and reactions Flashcards

1
Q

the law of conservation of matter

A

because the same atoms are present in a reaction at the beginning (reactants) and at the end (products), the amount of matter in the system does not change - this is why chemical equations must be balanced

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2
Q

reactants
products

A
  • the substances that exist before a chemical reaction takes place
  • the new substances that are formed during the chemical changes
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3
Q

types of phases in chemical equations

A

solid (s), liquid (l), and gaseous (g) phase

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4
Q

alternative symbol used to indicate a precipitate in chemical equation

A

arrow pointing down (alternative to (s))

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5
Q

alternative symbol used to indicate a gaseous product

A

arrow pointing up (alternative to (g))

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6
Q

above the reaction arrow can be written:

A
  • pressure (and its exact amount)
  • temp. at which react. was carried out
  • “delta” meaning that the reactants were heated
  • name of a substance that serves as the catalyst in the reaction
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7
Q

types of chemical reactions

A
  • synthesis (combination) - simple to complex
  • decomposition - complex to simple
  • single replacement reaction (AB + C -> A + BC)
  • double replacement reaction (AB + CD -> AC + BD)
  • neutralization reaction (acid + base -> salt + water)
  • combustion reaction - a hydrocarbon reacting with oxygen
  • polymerization (monomer + monomer = polymer)
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8
Q

relative atomic mass (Aˇr) =

A

actual mass/u (u=1/12 actual mass of C-12=1.66*10^-27 kg)

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9
Q
  1. n=
A

m/M [mol=g/gmol^-1)

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10
Q
  1. n=
A

N/NˇA (N = number of particles, Nˇ = Avogadro’s constant = 6.022*10^23 mol^-1)

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11
Q

In calculations with a limiting reactant, to find the number of moles of a product of interest, its stoichiometric coefficient and no of moles has to be put in the ratio/compared with…

A

…the stoichiometric coefficient and the number of moles of the limiting reactant

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12
Q

To identify the limiting reactant we have to…

A

…compare the no of moles with stoichiometric coefficients of the reactants and evaluate which reactant is present in excess and which is not (limited).

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13
Q

C =

A

n/V [M=mol/L]

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14
Q

mass concentration (of solvent) =

A

m(solvent)/V(of solution)

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15
Q

density (of solution) =

A

mass (of solution)/V (of solution) [g/cm^3]

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16
Q

stoichiometry

A

mass relationships between substances in a chem reaction (based on mole ratio - coefficients in a balanced chem equation)

17
Q

pV=

A

nRT [Pam^3=molJ/Kmol*K]

18
Q

R=

A

8.314 J/Kmol

19
Q

standard condition formula for n:

A

n= V^0/V^0ˇm (V is the volume of the gas, Vˇm is the standard molar volume (22.7 dm^3/mol)

20
Q

1 mol of gas at STP is…

A

…22.7 L. - Tˇ0=0°C or 25°C, Pˇ0=1 atm (101.3 Pa)