21 Carbonyl compounds Flashcards

1
Q

What are aldehydes oxidised to?

A

carboxylic acids

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2
Q

Which part of a carbonyl is a nucleophile attracted to?

A

Cб+

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3
Q

What does NaBH4 reduce an aldehyde to?

A

a primary alcohol

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4
Q

What does NaBH4 reduce a ketone to?

A

a secondary alcohol

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5
Q

Which reagent can be used to distinguish between aldehydes and ketones?

A

Tollens’ reagent

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6
Q

What species acts as the nucleophile in the reaction between carbonyl compounds and NaBH4?

A

H−

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7
Q

Why can carbonyl compounds react by nucleophilic addition?

A

because the C=O bond is polar

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8
Q

How does the π-bond in carbonyl compounds break to form a negatively charged intermediate during nucleophilic addition?

A

heterolytic fission

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9
Q

What is the suffix used when naming ketones?

A

What is the suffix used when naming ketones?

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10
Q

What reagent can be used to oxidise aldehydes?

A

acidified potassium dichromate

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11
Q

Can ketones be oxidised?

A

No

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