21 Carbonyl compounds Flashcards
What are aldehydes oxidised to?
carboxylic acids
Which part of a carbonyl is a nucleophile attracted to?
Cб+
What does NaBH4 reduce an aldehyde to?
a primary alcohol
What does NaBH4 reduce a ketone to?
a secondary alcohol
Which reagent can be used to distinguish between aldehydes and ketones?
Tollens’ reagent
What species acts as the nucleophile in the reaction between carbonyl compounds and NaBH4?
H−
Why can carbonyl compounds react by nucleophilic addition?
because the C=O bond is polar
How does the π-bond in carbonyl compounds break to form a negatively charged intermediate during nucleophilic addition?
heterolytic fission
What is the suffix used when naming ketones?
What is the suffix used when naming ketones?
What reagent can be used to oxidise aldehydes?
acidified potassium dichromate
Can ketones be oxidised?
No