11 Hydrocarbons Flashcards

1
Q

What is the shape around each carbon in an alkane?

A

tetrahedral

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2
Q

How does chain length of hydrocarbons affect boiling point?

A

increases as the length of the carbon chain increases

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3
Q

What triggers the breaking of a Cl—Cl bond?

A

UV light

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4
Q

What two types of bonding does a carbon–carbon double bond have?

A

a σ-bond and a π-bond

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5
Q

Why does E-Z isomerism occur?

A

different groups attached to each carbon around a double bond

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6
Q

What is the catalyst in hydrogenation?

A

nickel

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7
Q

Which type of carbocation is most stable?

A

tertiary

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8
Q

What are two uses of waste polymers?

A

feedstock or fuel

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9
Q

What is an electrophile?

A

an electron pair acceptor

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10
Q

What is stereoisomerism?

A

same structural formula but the atoms have a different arrangement in space

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11
Q

Which orbitals are overlapping in a carbon–carbon single bond?

A

two p-orbitals

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12
Q

What is incomplete combustion?

A

combustion in a limited supply of oxygen

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13
Q

What is homolytic fission?

A

when a bond breaks so that one electron goes to each of the atoms

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14
Q

What is a radical?

A

a compound or atom with an unpaired electron

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15
Q

What does a dashed wedge in the shape of molecules represent?

A

bonds that are going behind the page

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16
Q

Why does branching decrease boiling point of hydrocarbons?

A

the overall intermolecular forces decrease as there are fewer points of contact

17
Q

What rule is used to determine if a compound is an E- or Z-isomer?

A

Cahn–Ingold–Prelog priority rules

18
Q

What rule is used to determine the major or minor products when hydrogen halides react with an asymmetrical alkene?

A

Markownikoff’s rule

19
Q

Why is burning waste PVC problematic?

A

HCl gas given off