2: Water Flashcards

1
Q

most abundant compound in organisms (70% of body weight)

A

water

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2
Q

molecular geometry of water

A

bent or V-shaped (nearly tetrahedral arrangement of four electron groups around O)

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3
Q

how many hydrogen bonds can each water molecule make?

A

4 (2 on oxygen, 1 on each hydrogen)

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4
Q

8 unique properties of water that sustain life on Earth

A

high cohesion
high adhesion
high surface tension
high specific heat
high heat of vaporization
liquid at room temperature
excellent solvent
hydrophobic exclusion

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5
Q

act of sticking together

A

cohesion

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6
Q

act of sticking to something (due to ability of water to form H bonds)

A

adhesion

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7
Q

what component of plant cell walls can form H bonds with water molecules, allowing the latter’s transport?

A

cellulose (the hydroxyl groups)

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8
Q

measure of the resistance of a substance to increase its surface area due to high cohesion of its molecules

A

surface tension

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9
Q

2 types of molecules in a sample of water

A

inner and surface

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10
Q

explain the high surface tension in water

A

there is formation of stronger bond between surface water molecules as they are pulled inward by a net inward force due to absence of attractive force acting from above and thus preventing them from being stretched or broken

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11
Q

2 importance of high surface tension of water

A
  • allows denser things and animals to float
  • formation of water droplets
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12
Q

amount of heat per unit mass required to raise the temperature by 1degree Celsius

A

specific heat

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13
Q

specific heat of water

A

2 cal/g-degree Celsius

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14
Q

what happens when temperature of water increases? decreases?

A

increase in T: water molecules would move faster due to increase in kinetic energy, leading to the breaking of H bonds which absorbs heat

decrease in T: water molecules would move slower due to decrease in KE, causing the formation of H bonds which releases heat

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15
Q

2 importance of moderation of temperature by water

A

regulate air temperature change near oceans

regulation of internal body temperature

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16
Q

process at which as liquid evaporates, the liquid surface that remains behind cools down

A

evaporative cooling

17
Q

what makes evaporative cooling possible

A

high heat of vaporization of water

18
Q

amount of heat needed to turn 1 g of liquid into a vapor without a rise in temperature of the liquid

A

heat of vaporization

19
Q

heat of vaporization of water

A

540 cal/g at 25 degrees Celsius (high due to hydrogen bonding)

20
Q

2 importance of evaporative cooling

A

sweating

evaporation of water on the surface of leaves

21
Q

how many hydrogen bonds does water molecules form on ice? on liquid water?

A

ice: 4 H bonds, stable

liquid water: 3.2 H bonds on average, constant breaking and reformation of H bonds

22
Q

ice is ____ than water

A

less dense

23
Q

why does water readily dissolve other polar compounds and salts?

A

high dielectric constant

24
Q

measure of the ability of a solvent to keep opposite charges apart

A

dielectric constant

25
refers to when ions are nonrandomly surrounded by water molecules that attenuates the coulombic forces between these ions
hydration
26
tendency of amphiphiles to self-associate in water than to dissolve individually
hydrophobic effect
27
why do amphiphile molecules cluster together instead of each amphiphile molecule being surrounded by water molecules?
the latter is not favored because of the resulting highly ordered structure (decrease in entropy of the system) and the former also requires fewer water molecules
28
spherical amphiphilic structures that have a hydrophobic core and a hydrophilic shell
micelles
29
3 instances of water as medium for biochemical processes
weak interactions in the aqueous system water and its ionization products (H3O+ and OH-) weak acid-base equilibria/physiological buffers
30
4 weak interactions of water in aqueous systems that are individually weak but are collectively significant
hydrogen bonding ionic interactions hydrophobic interactions van der Waals forces
31
4 examples where H bonds are found in biological systems
between alcohol and water between carbonyl ketone and water between peptide groups between nitrogenous bases
32
bond between nucleic acids
phosphodiester bond