2 Thermal Physics Flashcards
Gases and the absolute scale of temperature (Pressure Law, Boyle’s Law (pv = constant), Charles’ Law)
Describe qualitatively, in terms of particles, the
effect on the pressure of a fixed mass of gas of:
(a) a change of temperature at constant volume
(b) a change of volume at constant temperature
a) change of temperature - increase of temperature, increase of pressure
b) change of volume - increase of volume, decrease of pressure
In a flexible sealed container, the amount of gas molecules are fixed.
If we keep the temperature constant, the only way to increase pressure is to reduce volume.
𝑷∝𝟏/𝑽 𝑤ℎ𝑒𝑛 𝑇 𝑖𝑠 𝑐𝑜𝑛𝑠𝑡𝑎𝑛𝑡
𝑷𝑽=𝒄𝒐𝒏𝒔𝒕𝒂𝒏𝒕
Formula: 𝑷𝟏V𝟏 = 𝑷𝟐V𝟐
In a rigid sealed container, both the volume and amount of gas molecules are fixed.
The only way to increase the gas pressure is by increasing its temperature.
𝑷∝𝑻 𝑤ℎ𝑒𝑛 𝑉 𝑖𝑠 𝑐𝑜𝑛𝑠𝑡𝑎𝑛𝑡
𝑷/𝑻=𝒄𝒐𝒏𝒔𝒕𝒂𝒏𝒕
i) Name the process by which thermal energy is transferred through a metal rod
ii) Describe how this process occurs
iii) observation: flame appears both above and below the gauze ;; observation: flame only appears below the gauze
How can these observations be explained? [4]
i) conduction
(ii) molecules at hot end vibrate more bc have more energy
energy/vibration transferred to neighbours/shared
iii) iron conducts heat slowly
gas hot enough to burn /
copper conducts heat rapidly
gas not hot enough to burn
Evaporation VERSUS boiling
Both processes involve the change of state from liquid to gas.
Boiling is rapid and takes place in the entire body of liquid.
Boiling only occurs at the boiling point.
Evaporation is slow and takes place only on the surface of liquid. Evaporation occurs at any temperature between the melting and boiling point.
What is latent heat? [2]
Latent heat = energy needed to change the state (gas, liquid, solid) of one kilogram of material
In Mark Scheme: “energy required to change state with no change in temperature”
What is latent heat of fusion?
Define: Latent heat of fusion (melting)
Unit?
the amount of heat energy required to change a substance from a solid state to a liquid state at its melting point, without changing its temperature.
Mark Scheme: energy needed to change state of substance, to melt, per kg
J/kg
Latent heat of vaporisation? [2]
energy to change 1 kg from liquid to gas / gas to liquid (without changing its temperature)
The rate of heating is 2.0 kW.
Calculate how much energy is supplied to the substance during the period 18 – 22 minutes
Formula? kW multiplied by time = energy
Rate of heating (W) x time (s) = energy (J)
2000 x 240
480,000 J
The Gas Laws - Pressure & Volume (Constant Temperature)
If the temperature of a gas remains constant, the pressure of the gas changes when it is…
- Compressed – decreases the volume which increases the pressure
- Expanded – increases the volume which decreases the pressure
A change in pressure can cause a change in volume
A _____ can be used to remove the air from a sealed container
Describe change in volume to a tied up balloon when the pressure of the air around it decreases:
vacuum pump //
At normal air pressure the balloon has a low volume [bell jar open to the surroundings]
As the pressure in the bell jar decreases, the volume of the balloon increases
[air removed from bell jar by vacuum pump]
Melting & Boiling
What are fixed points?
melting and boiling points of pure water at atmospheric pressure
Melts at 0, boils at 100
Convert temperatures between kelvin and degrees Celsius
Eqn to recall
;; a temperature at which the particles in a gas exert no pressure - at this temperature they must no longer be moving, and hence not colliding with their container
This temperature is called absolute zero and is equal to -273 °C!
T (in K) = θ (in °C) + 273
Celsius temp + 273 => Kelvin
Eqn for a fixed mass of gas at constant temperature,
including a graphical representation of this
relationship
pv = constant
Eqn recall for finding vol/pressure given necessary info
relationship between the pressure and volume for a fixed mass of gas at constant temperature
P1V1 = P2V2
STATE FORMULA WHEN USING in test
VOLUME => m3
Pressure (Pa)
kJ to J
1 Pa = 1 kg/m.s^2
1 kPa = ___ kg/m.s^2
x 1,000
1 Pa = 1 kg x m-1 x s-2
1 kPa = 1,000 kg/m.s^2
Specific latent heat eqn
E = mL.
where E is the energy in joules (J), m is the mass in kilograms (kg), and L is the specific latent heat in joules per kilogram (J/kg).
Properties of Solids, Liquids & Gases
Solids
Solids have a definite shape and a definite volume
Solids cannot flow and are not compressible
Liquids
Liquids have no definite shape but do have a definite volume
Liquids are able to flow to take the shape of a container but they are not compressible
Gases
Gases have no definite shape and no fixed volume
Gases can flow to take the shape of their container and are highly compressible
Changes of State
When a substance changes state, the number of molecules in that substance _____ change and so neither does its mass
The only thing that changes is its _____
Changes of state are physical changes and so they are _____
DOESN’T change
ENERGY
REVERSIBLE
Arrangement & Motion of Particles
Solids
The molecules are very close together and arranged in a regular pattern
The molecules vibrate about fixed positions, high density
Liquids
& Gases
The molecules are still close together (not reg)
The molecules are able to slide past each other, medium density
The molecules are widely separated - about 10 times further apart in each direction
The molecules move about randomly at high speeds, low density
Intermolecular Forces and Motion of Particles
Solids
The molecules in a solid are held in place by strong intermolecular forces
They only vibrate in position
The distance between them is fixed
This gives the solid its rigid shape and fixed volume
Liquids
The molecules in a liquid have enough energy to overcome the forces between them
They are still held close together
The volume of the liquid is the same as the volume of the solid
Molecules can move around (by sliding past each other)
This allows the liquid to change shape and flow
Gases
The molecules in a gas have more energy and move randomly at high speeds
The molecules have overcome the forces holding them close together
Because of the large spaces between the molecules
The gas can easily be compressed and is also able to expand
Gases flow freely
While a substance is changing state, either
-Melting or freezing
- Boiling or condensing
Does the substance change temperature?
No, even though energy is being transferred to or away from the thermal energy store of the substance
At the boiling point, even if more thermal energy is added, does the water get hotter?
the liquid water does not get any hotter
internal energy is not rising
additional thermal energy goes into overcoming the intermolecular forces between the molecules of water, becomes gas
For condensation
For freezing
process is repeated backwards for cooling as energy/heat is transferred away
At the melting point, even if more thermal energy is added, does the water get warmer?
Again, the solid water does not get warmer
internal energy is not rising
additional thermal energy goes into overcoming the intermolecular forces btwn the molecules of the solid ice, becomes liquid
Heating is when …
energy is transferred to the system and the kinetic energy of the molecules increases
Cooling is when …
energy is transferred away from the system (or dissipated to the surroundings) and the kinetic energy of the molecules decreases
Describe condensation
The particles lose kinetic energy and move more slowly
They no longer have enough energy to overcome the intermolecular forces of attraction between molecules
The particles get closer together
They only have enough energy to flow over one another
The gas has condensed into a liquid with no change of temperature
Describe solidification
The particles lose kinetic energy and move more slowly
They no longer have enough energy to overcome the intermolecular forces of attraction between molecules
The particles get closer together
They only have enough energy to vibrate about their fixed position
The liquid has solidified into a solid with no change of temperature
Boiling vs Evaporation
Boiling is also a change in state from liquid to gas
Boiling happens only at the boiling point of the liquid
The change of state happens all through the liquid
the higher the pressure, the higher the ____
force exerted per unit area
What is Brownian Motion?
The Kinetic Theory of Matter, which simply says that …
the random movement of particles in a liquid or a gas produced by large numbers of collisions with smaller particles which are often too small to see
All matter is made up of tiny particles
+ EXTENDED
When observing Brownian Motion, even w/ a microscope, only the microscopic particles can be seen. The pollen or smoke particles are seen to move
Smaller atoms and molecules, of water or air, are still too small to be seen.
These light, fast-moving atoms and molecules collide with the larger microscopic particles
The collisions give the particles a little nudge, causing them to change their speed and directions randomly, each time they are struck by a molecule
The presence of the light, fast moving atoms and molecules is inferred from the motion of the microscopic particles
Can be seen: pollen, smoke particles
Pollen particle gets hit by air molecule
We cannot see them though
Gases & Absolute Temperature
An increase of 1 K is the same change as an increase of 1 °C
It is not possible to have a temperature lower than 0 K
meaning…?
This means a temperature in kelvin will never have a negative value
[also add 273 if beginning w Celc]
Boyle’s Law
If the temperature T of an ideal gas is constant, then Boyle’s Law is given by:
Graph looks like?
P proportional to 1/V
This means the pressure is inversely proportional to the volume of a gas
pressure on x-axis to volume graph, downward curve that’s like I‿
Thermal expansion
When materials are heated, they _____ because _____
____ expand most, _____ expand least
EXPAND bc the molecules start to move around (or vibrate) faster, causing them to knock into each other & push each other apart
Gases most,
solids least
Thermal Expansion in Terms of Particles
Solids
Expand slightly
bc the low energy molecules cannot overcome the intermolecular forces of attraction holding them together
Liquids
Expand more than solids
bc the molecules have enough energy to partially overcome the intermolecular forces of attraction holding them together
Gases
Expand significantly
bc the high energy molecules have enough energy to completely overcome the intermolecular forces of attraction holding them together
Uses & Consequences of Thermal Expansion
Applications:
Thermometers rely on the expansion of liquids to measure temperature
Temperature-activated switches work when a bimetallic strip, consisting of two metals that expand at different rates, bends by a predictable amount at a given temperature
- Thermostat in An Iron
- Fire Alarm
Consequences:
The expansion of solid materials can cause them to buckle if they get too hot
This could include:
Metal railway tracks
Road surfaces
Bridges
Things that are prone to buckling in this way have gaps built in, this creates space for the expansion to happen without causing damage
Simple explanation: [Reminder molecules do not expand, SUBSTANCE does]
As heat is added,
As heat is added:
The increase in temperature…
Leads to an increase in kinetic energy, so that…
Molecules and atoms move more quickly…
And move apart
This separation of the the molecules makes the substance bigger
Internal energy is defined as:
The total energy stored inside a system by the particles that make up the system due to their motion and positions
Avg kinetic energy: Heating a system changes a substance’s internal energy by increasing the kinetic energy of its particles
Therefore, temp of material is…
The temperature of the material is related to the average kinetic energy of the molecules
This increase in kinetic energy (and therefore internal energy) can:
Cause the temperature of the system to increase
Or, produce a change of state (solid to liquid or liquid to gas)
As the container heats up, the gas molecules move faster
Faster motion causes higher kinetic energy and therefore ________________
higher internal energy
How much the temperature of a system increases depends on:
The mass of the substance heated
The type of material
The amount of thermal energy transferred in to the system