2 Foundations In Chemistry- Acids 4.1-4.3 Flashcards
Acids and bases
are on the opposite ends of the pH scale. They combine to form water, which is neutral.
Acids
Acids are substances that form hydrogen (H+) ions when they dissolve in water (aqueous solutions).
Acids are proton donors.
neutralise bases to form salt and water. An acid can be strong or weak - this will affect its dissociation.
Bases
Alkalis are substances that form hydroxide (OH-) ions when they dissolve in water (aqueous solutions).
Bases can neutralise acids.
An alkali is a type of base. An alkali is a base that’s soluble in water.
Bases are proton acceptors.
Bases are metallic oxides or hydroxides (or ammonia) that neutralise acids to form salt and water.
Sulphuric acid
H2SO4
Nitric acid
HNO3
Ethanoic acid
CH3COOH
Sodium hydroxide
NaOH
Potassium hydroxide
KOH
Ammonia
NH3
Water dissociation
Water dissociates to give a proton and a hydroxide.
H2O ⇋ H+ + OH−
Weak base
Weak bases don’t fully ionise in aqueous solutions.
Ammonia solution is an example of a weak base.
It exists mainly as NH3 molecules. Only a few of these react with water molecules to form ions.
NH3(aq) + H2O(l) ⇌ NH4+(aq) + OH-(aq).
Strong base
Aqueous sodium hydroxide and potassium hydroxide are examples of strong bases.
Strong bases fully ionise in aqueous solutions.
NaOH(aq) → Na+(aq) + OH-.
KOH(aq) → K+(aq) + OH-.
Weak acid
Weak acids don’t fully ionise in aqueous solutions.
Ethanoic acid is an example of a weak acid.
Ethanoic acid exists mainly as CH3COOH molecules. Only a few of these react with water molecules to form ions.
CH3COOH(aq) + H2O(l) ⇌ H3O+(aq) + CH3COO-(aq)
Strong acid
Aqueous HCl, HNO3 and H2SO4 are examples of strong acids.
Strong acids fully ionise in aqueous solutions.
HCl(aq) → H+(aq) + Cl-.
HNO3(aq) → H+(aq) + NO3-.
Acid + metal oxide
Produces salt + water
Acid + metal carbonate
Produces salt + water + carbon dioxide
Titration technique
In a titration, you want to calculate the concentration of an acid or base by reacting it with a known amount of base or acid. To do this:
Add a measured amount of one to the other.
Use a balanced equation to calculate the concentrations.
Titrations- accuracy
In a titration, you want to make sure you have accurate results.
Accurate results are achieved by repeating your titration until you get concordant results.
Concordant results are values that are within 0.1 cm3 of each other.
Phenolphthalein and methyl orange indicators
Phenolphthalein changes from colourless to pink from pH 8.3 to pH 10.
Methyl orange changes colour from red to yellow between pH 3.1 and pH 4.4.
Oxidising agents
An oxidising agent oxidises something else.
It takes electrons from another compound.
This means it gains electrons itself.
So an oxidising agent is itself reduced.
Reducing agents
A reducing agent reduces something else.
It gives electrons to another compound.
This means it loses electrons itself.
So a reducing agent itself is oxidised.
Oxidation states
An oxidation state shows how many electrons an atom has gained or lost.
The concept of oxidation state is related to electronegativity.
Electronegativities can be used to work out oxidation states.
Ionic half equations
An ionic half equation shows either reduction or oxidation.
An example is: O2 + 4e- → 2O2-
This is the ionic half equation for the reduction of O2 to 2O2-
If you have ionic half equations for both a reduction process and an oxidation process, you can add the two to generate a full balanced equation.