19.1.1 Reviewing Oxidation-Reduction Reactions Flashcards
Reviewing Oxidation-Reduction Reactions
- Oxidation-reduction reactions (redox reactions) are reactions in which electrons are transferred from one reactant to another.
- Redox reactions in which the changes are minor and easily controlled can be used to harness electricity.
- Redox reactions can be balanced by breaking the reaction into half-reactions.
note
- In oxidation-reduction reactions (redox reactions), electrons are transferred from the reductant to the oxidant.
- The reductant loses electrons, and is oxidized itself.
- The oxidant gains electrons, and is reduced itself.
- Redox reactions involving a minimal rearrangement of atoms, a low kinetic barrier, and controlled changes (such as the oxidation of copper metal by silver ions) can be harnessed to produce electricity.
- Redox reactions involving a high kinetic barrier or a mixture of products (such as the oxidation of methane by oxygen) are harder to harness to produce electricity.
- Redox reactions can be balanced by breaking the reaction into half-reactions.
- This is done by identifying redox partners (Br 2 and Br – , for example), and writing a half-reaction for each.
- Each half-reaction is then balanced for oxygen atoms and hydrogen atoms using H 2 O and H + (in acid) or H 2 O and OH – (in base).
- Finally, the number of reactant electrons in the reduction half-reaction must be balanced with the number of product electrons.
What is the oxidation number for chromium in K2Cr2O7 for the following reaction?
+6
Which of the following is the balanced equation for the reaction between the permanganate ion and chloride ion in an acidic solution?
2MnO4- + 10Cl- + 16H+ -> 2Mn2+ + 5CL2 + 8H2O
What is the common oxidation state for an alkaline earth metal?
+2
What happens in all redox reactions?
There is a transfer of electrons.
What is the common oxidation number for oxygen in a compound?
−2
What is the oxidation number for nitrogen in Cu(NO3 )2 for the following reaction?
+5
Which of the following is not true about reduction?
An increase in oxidation number occurs in the reduction half-reaction.
Which of the following is necessary to balance a redox reaction?
Make the increase and decrease in oxidation numbers the same.
What is an oxidation in a redox reaction?
An increase in oxidation number