19:Enthalpy Pt.1 Flashcards

1
Q

What is the symbol for enthalpy change

A

ΔH

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2
Q

Is ΔH positive or negative in an exothermic reaction

A

negative

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3
Q

Is ΔH positive or negative in an endothermic reaction

A

positive

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4
Q

What is the unit for enthalpy change

A

kJmol¯¹

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5
Q

Will combustion have a positive or negative enthalpy change

A

negative because it is exothermic

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6
Q

What are standard conditions

A

Pressure: 1 atmosphere (100 kPa)
Temp: 25℃ (unless stated otherwise)

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7
Q

What is the symbol for standard enthalpy change

A

ΔHϴ

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8
Q

What is standard enthalpy change

A

Enthalpy change measured under standard conditions

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9
Q

What is standard state

A

A substance’s physical state under standard conditions.

eg. water is a liquid in standard state

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10
Q

What is enthalpy change of reaction (ΔrH) of a substance

A

The enthalpy change when the number moles shown in the equation react to form the products.

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11
Q

What is enthalpy change of combustion (ΔcH) of a substance

A

The enthalpy change when 1 mol of a substance is burned completely in oxygen

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12
Q

What is enthalpy change of formation ( ΔfH) of a substance

A

The enthalpy change when 1 mol of a substance is formed from its elements

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13
Q

What is enthalpy change of neutralisation (ΔneutH) of a substance

A

The enthalpy change when 1 mol of water is formed in a neutralisation

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14
Q

What is the equation for heat evolved or absorbed

A

q = mCΔT

q: heat (J)
m: mass (usually in g)
C: specific heat capacity (J g¯¹ K¯¹)
ΔT: Temperature change (℃)

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15
Q

What is the specific heat capacity of water

A

4.18 J g¯¹ K¯¹

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16
Q

How to get from heat evolved to enthalpy change

A

convert to kJ

divide by mol

17
Q

What assumptions are made when calculating the heat evolved for a reaction in a solution

A
  • The density of the solution is assumed to be the same as water which is 1 gcm¯³
  • The specific heat capacity of the solution is assumed to be the same as water (4.18)