17. Law of radiation attenuation. Flashcards
Law of radiation attenuation and its validity.
Define attenuation
Attenuation is the loss of intensity as radiation propagates through a medium. It is caused by absorption and scattering.
Scattering is negligible in dilute solutions.
→ E “lost” is absorbed
→ remaining E is transmitted
Define absorbance, give 2 different terms, and its formula
Absorbance is the logarithmic ratio of the amount of radiation falling upon a material to the amount of radiation transmitted through the material.
On the atomic scale this means that Ephoton is used to excite an outer shell e- of the absorbing material.
Absorption is wavelength dependent.
Also referred to as:
- optical density (OD)
- extinction (E)
Formula: A = lg(J0/J)
BUT: the amount of absorbance can be calculated from the general radiation attenuation law
Define transmittance and give its formula
Transmittance is the fraction of incident light (EM radiation) at a specified wavelength that passes through a sample.
Formula: T = J/J0 * 100%
Explain how the differential form of the law of radiation attenuation is obtained, its validity, and give its formula. Refer to the diagram below.
Differential form of the law of radiation attenuation:
the decrease of intensity is proportional to the thickness of absorber Δx and J what is the atten
BUT:
- only parallel beams perpendicular to the surface are considered (simplification)
- only applicable for very thin layers
Formula: ΔJ = J0 − J = −μ ⋅ Δx ⋅ J
- μ = linear attenuation coefficient
- J0 = intial intensity of radiation
Explain how the integral form of the law of radiation attenuation is obtained, its validity, and give its formula. Refer to the diagram below.
Integral form of law of radiation attenuation:
in fact intensity decreases exponentially with the increase of thickness, only in case of very thin linearly propotional
Formula: J = J0 ⋅ e−μx
- μ = linear attenuation coefficient
- J0 = intial intensity of radiation
The linear attenuation coefficient μ depends on.. ? What is its unit?
- quality of the material
- wavelength
Unit: 1/m
Define half-value thickness and give another term
Half-value thickness is the thickness of the material at which the intensity of radiation entering it is reduced by one half
- also related to as half-value layer HVL
On which 3 qualities does radiation attenuation depend on?
Dependence of radiation attenuation:
- photon E of radiation
- material of absorber (→ μ)
- density / concentration of absorber