17. Law of radiation attenuation. Flashcards
Law of radiation attenuation and its validity.
Define attenuation
Attenuation is the loss of intensity as radiation propagates through a medium. It is caused by absorption and scattering.
Scattering is negligible in dilute solutions.
→ E “lost” is absorbed
→ remaining E is transmitted
Define absorbance, give 2 different terms, and its formula
Absorbance is the logarithmic ratio of the amount of radiation falling upon a material to the amount of radiation transmitted through the material.
On the atomic scale this means that Ephoton is used to excite an outer shell e- of the absorbing material.
Absorption is wavelength dependent.
Also referred to as:
- optical density (OD)
- extinction (E)
Formula: A = lg(J0/J)
BUT: the amount of absorbance can be calculated from the general radiation attenuation law
Define transmittance and give its formula
Transmittance is the fraction of incident light (EM radiation) at a specified wavelength that passes through a sample.
Formula: T = J/J0 * 100%
Explain how the differential form of the law of radiation attenuation is obtained, its validity, and give its formula. Refer to the diagram below.
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Differential form of the law of radiation attenuation:
the decrease of intensity is proportional to the thickness of absorber Δx and J what is the atten
BUT:
- only parallel beams perpendicular to the surface are considered (simplification)
- only applicable for very thin layers
Formula: ΔJ = J0 − J = −μ ⋅ Δx ⋅ J
- μ = linear attenuation coefficient
- J0 = intial intensity of radiation
Explain how the integral form of the law of radiation attenuation is obtained, its validity, and give its formula. Refer to the diagram below.
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Integral form of law of radiation attenuation:
in fact intensity decreases exponentially with the increase of thickness, only in case of very thin linearly propotional
Formula: J = J0 ⋅ e−μx
- μ = linear attenuation coefficient
- J0 = intial intensity of radiation
The linear attenuation coefficient μ depends on.. ? What is its unit?
- quality of the material
- wavelength
Unit: 1/m
Define half-value thickness and give another term
Half-value thickness is the thickness of the material at which the intensity of radiation entering it is reduced by one half
- also related to as half-value layer HVL
On which 3 qualities does radiation attenuation depend on?
Dependence of radiation attenuation:
- photon E of radiation
- material of absorber (→ μ)
- density / concentration of absorber