16th Group Flashcards
Common electronic configuration
ns2 np4
Valences
2 & 4 (but O differs)
What are the metallic characters of 16th group elements
O and S are non-metals
Se, Te, Po show both metal and non-metal characters
What is the only element in 16th group which exists in gaseous state?
O
Oxidation states
Except O, other elements in the group can form even numbered oxidation states from -2 upto +6
What are the 16th group hydrides?
H2O
H2S
H2Se
H2Te
2 allotropic forms of oxygen
O2 and O3
Describe O3
Ozone is a light blue colored (colorless) gas with a pungent odor
What special properties does O3 have due to its ability to produce atomic oxygen?
- Oxidizing agent
- Reducing agent
- Disinfecting agent
Describe O2
O2 is colorless, and odorless
Slightly water soluble
How is O2 prepared in the laboratory?
Catalytic decomposition of KClO3
KClO3 ———-> KCl + O2
(heating with MnO2 or Pt)
Catalytic decomposition of H2O2
H2O2 ——-> H2O + O2
(heating with MnO2)
How is O2 produced industrially?
By fractional distillation of liquid air
What is the most widely used solvent?
water
Show the ionization of H2O
2H2O —> OH- + H30+
revers.
Show water’s reactions with acids and bases
NH3 + H2O —> NH4+ + OH-
HCl + H20 —–> Cl- + H3O+
water’s reaction w bases
NH3 + H2O —> NH4+ + OH-
water’s reaction w acids
HCl + H20 —–> Cl- + H3O+
Why is water considered amphiprotic?
It can either donate or accept a proton
Decomposition of H2O2 in sunlight
H2O2 —>H2O + O2
So, H2O2 is usually stored in brown or black colored bottles
Describe H2O2
- viscous, colorless liquid
- compared to water, MP, BP and density higher. This is due to presence of OH groups
- Due to excess mass, comparatively stronger London forces are also possible.
How does H2O2 release atomic oxygen
H2O2 —-> H2O + O
uses of H2O2
Oxidizing agent
Disinfecting agent
Bleaching agent
Reducing agent
Used as a rocket fuel
Properties of H2O2
- Oxidizing agent
- Reducing agent
- Antiseptic agent
- Bleaching agent
How does H2O2 react as an oxidizing agent?
- with acidified iodide ions
H2O2 —> H2O
I- —> I2
- Reaction with Fe2+ ions
H2O2 —> H2O
Fe2+ —> Fe3+