1.6 Periodic Table Flashcards

1
Q

how are elements arranged

A

according to atomic number

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2
Q

vertical columns are

A

groups

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3
Q

horizontal rows

A

periods

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4
Q

trend in ionization energy across period

A

increases across a period because there is an increase in nuclear charge in the same energy level.

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5
Q

ionization energy down a group

A

decreases down a group because the outer
electron has increased shielding from inner electrons.

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6
Q

trend in electronegativity

A

increases across a period because there is an
increase in nuclear charge, but the bonding electrons are always shielded by the same inner electrons.

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7
Q

trend in melting and boiling point

A

generally increase from the first to the fourth element, followed by a large decrease to the fifth element and a small general decrease to the eighth element. This is because the bonding changes from metallic to giant covalent to simple molecular covalent.

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8
Q

oxidation

A

loss of electrons

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9
Q

reduction

A

gain of electrons

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10
Q

oxidising agent

A

is a species that accepts electrons; it becomes
reduced itself in the process

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11
Q

reducing agent

A

species that donates electrons; it becomes
oxidised itself in the process.

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12
Q

oxidised

A

if oxidation number increases

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13
Q

reduced

A

reduction number decreases

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14
Q

group 1 metals with water

A

react vigorously with cold water to form the
hydroxide and hydrogen.

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15
Q

group 2 metals with water

A

react less vigorously, in fact, magnesium reacts very slowly, while calcium produces a steady stream of bubbles and a
white precipitate of calcium hydroxide. Again, the hydroxide and hydrogen are formed

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16
Q

trend in reactivity

A

increases as you go down a group because when the s-block metals react they lose electrons to form positive ions. Since
ionisation energies decrease down a group, the energy needed to form positive ions decreases.

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17
Q

compare group 1 and 2 metals

A

Group 1 metals are more reactive than Group 2 metals because
they lose only one electron while Group 2 metals lose two2

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18
Q

group 1 and 2 reacting with oxygen

A

All Group 1 and Group 2 metals burn to form solid white oxides.

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19
Q

group 1 oxide and barium oxide reacting

A

Group 1 oxides and barium oxide react with water to form a soluble hydroxide or alkali.

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20
Q

soluble hydroxide ?

A

its an alkali

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21
Q

alkali?

A

soluble hydroxide

22
Q

sodium flame test

A

orange yellow

22
Q

lithium flame test

A

red

23
Q

potassium flame test

A

lilac

24
Q

calcium flame test

A

brick red

25
Q

strontium flame test

A

crimson

26
Q

barium flame test

A

apple green

27
Q

solubility of group 1

A

soluble

28
Q

solubility of group 2

A

non-soluble

29
Q

trends for group 2 compounds

A
  • All nitrates are soluble.
  • All carbonates are insoluble.
  • Hydroxides are more soluble as you go down the group.
30
Q

solubility trend for sulfates

A

become less soluble as you go down the group

31
Q

trend in thermal stability

A

increases as you go down the group

32
Q

group 7 halogens

A

As the number of electrons increases with atomic number, there is an increase in the induced dipole – induced dipole intermolecular forces holding the diatomic molecule together. Thus, the melting
and boiling temperatures increase as you go down the group.

33
Q

chlorine at room temp

A

green gas

34
Q

bromine at room temp

A

red-brown liquid

35
Q

iodine at room temp

A

grey solid

36
Q

halogens react by gaining electrons

A

forms negative halide

37
Q

during reactions what do halogens do ?

A

in reactions halogens are reduced and they oxidise the other substance

38
Q

halogens down the group – sheilding?

A

As you go down the group the outer electrons are shielded more and are further from the nucleus.

39
Q

halogens react directly with most metals to form

A

halides

40
Q

displacement reactions

A

A halogen in a higher position in the group will oxidise a halide ion from lower in the group

41
Q

how to test for halide ions

A

few drops of nitric acid to halide ions then add silver nitrate solution followed by diltute aq ammonia

42
Q

test for halide ions
cl- chlorine

A

silver nitrate = white precipitates
diluted nh3 = ppt dissolves

43
Q

test for halide ions
bromine

A

silver nitrate = cream precipitate
diluted nh3 = ppt dissolves slightly

44
Q

test for halide ions
iodine

A

nitric acid = pale yellow precipitate
diluted nh3 = no change

45
Q

chlorine in water treatment

A

Chlorine gas is added to drinking water to kill dangerous bacteria and viruses such as cholera and typhoid, thereby preventing
the outbreak of serious diseases.

It needs to be added in low concentrations (below 1 part per million) in order to be safe.

46
Q

fluoride in water treatment

A

Fluoride is added to water to reduce tooth decay, by preventing cavities. It is also said to strengthen bones, which helps prevent osteoporosis.

Again, it appears to only have beneficial effects when added below 1 ppm.

47
Q

how are insoluble salts formed

A

by a precipitation reaction

48
Q

how are soluble salts formed

A

by neutralising an acid

49
Q

what occurs in precipitation reaction

A

two suitable solutions are mixed to form a soluble salt and an insoluble salt.
For example, the formation of calcium carbonate