16 - Organic Analysis Flashcards
What is the test for a halogenoalkane?
Add warm aqueous NaOH
Acidify with HNO3
Add AgNO3
Precipitate of AgX
What is the test for an alcohol?
Add acidified Kr2Cr2O7
Orange turns green with primary or secondary (or aldehydes)
Give two tests for aldehydes.
Warm with Tollen’s
Silver mirror forms
Warm with Fehling’s
Blue goes red precipitate
What is the test for a carboxylic acid?
Add aqueous NaHCO3
CO2 given off
What is on the x axis of a mass spectrum?
mass/charge ratio
What is the range of a fingerprint region?
Wavenumber < 1500cm-1
What region is unique to an organic molecule? (infrared)
Fingerprint region
How does infrared spectrometry work?
Identifies compounds based on changes in vibrations when they absorb IR of certain frequencies.
Bonds absorb infrared at specific frequencies.