15.3 The Alkenes Flashcards

1
Q

What is unsaturated hydrocarbon?

A

Compounds of hydrogen and carbon only molecules contain carbon to carbon double bonds or triple bonds

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2
Q

What is cracking?

A

The process in which large less useful hydrocarbon molecules are broken down into smaller more useful molecules in an oil refinery

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3
Q

Explain how the process of cracking takes place

A

The larger hydrocarbon molecules are fed into a steel chamber that contains no oxygen so combustion does not take place. The larger hydrocarbon molecules are heated to a high temperature and are passed over an aluminium oxide catalyst.

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4
Q

When large alkane molecules are cracked, what is produced?

A

Smaller alkane molecules and alkane molecules

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5
Q

Why are alkenes more reactive than alkanes?

A

Because of their double bonds

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6
Q

Why does alkenes being more reactive make them very valuable

A

This makes them useful for the chemical industry as the starting compounds (feedstock) many new products. These include most plastics.

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7
Q

What are some methods of making alkenes?

A

Cracking of alkanes
Elimination of a hydrogen halide from a halogen alkane by heating with ethanolic
Sodium hydroxide
Dehydration of an alcohol by using a heated catalyst (aluminium oxide) or a concentrated acid

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8
Q

What is dehydration?

A

It is the elimination of a water molecule from a reactant molecule

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9
Q

Most reactions of alkenes examples of

A

addition reactions

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10
Q

What happens in the addition reaction of alkenes?

A

One of the two bones in the carbon to carbon double bonds is broken and a new single bond is formed from each of the two carbon atoms.

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11
Q

What happens in the addition of hydrogen to an alkene

A

When hydrogen gas and an alkene are heated and passed over a finely divided platinum/nickel catalyst the addition reaction produces an alkane

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12
Q

What is hydrogenation?

A

The addition reaction of alkenes with hydrogen

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13
Q

Give one example when hydrogenation is used

A

In the manufacture of margarine

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14
Q

What happens in the addition of alkenes to hydrogen halides

A

When an alkene is through a concentrated solution of hydrogen halide at room temperature the product is halogen alkane

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15
Q

When are 2 possible products possible in the reaction of addition of hydrogen halides?

A

When there are longer asymmetric alkenes reacting with a hydrogen halide

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16
Q

What is the major product when 2 addition products are possible in alkenes

A

The major product is the one that has the halogen atom bonded to the carbon to carbon double bond carbon atom with the highest number of alkyl groups bonded to it

17
Q

What is an intermediate in a reaction?

A

A species which is formed at a particular step of the reaction. Intermediate are stable enough to react with another substance but not enough to be a product..

18
Q

How is alcohol made in the industry?

A

By the addition of steam to gaseous alkenes high temperatures and pressure in the presence of concentrated phosphoric acid. H3PO4

19
Q

How is alcohol made in the industry?

A

By the addition of steam to gaseous alkenes high temperatures and pressure in the presence of concentrated phosphoric acid as a catalyst