15.3 The Alkenes Flashcards
What is unsaturated hydrocarbon?
Compounds of hydrogen and carbon only molecules contain carbon to carbon double bonds or triple bonds
What is cracking?
The process in which large less useful hydrocarbon molecules are broken down into smaller more useful molecules in an oil refinery
Explain how the process of cracking takes place
The larger hydrocarbon molecules are fed into a steel chamber that contains no oxygen so combustion does not take place. The larger hydrocarbon molecules are heated to a high temperature and are passed over an aluminium oxide catalyst.
When large alkane molecules are cracked, what is produced?
Smaller alkane molecules and alkane molecules
Why are alkenes more reactive than alkanes?
Because of their double bonds
Why does alkenes being more reactive make them very valuable
This makes them useful for the chemical industry as the starting compounds (feedstock) many new products. These include most plastics.
What are some methods of making alkenes?
Cracking of alkanes
Elimination of a hydrogen halide from a halogen alkane by heating with ethanolic
Sodium hydroxide
Dehydration of an alcohol by using a heated catalyst (aluminium oxide) or a concentrated acid
What is dehydration?
It is the elimination of a water molecule from a reactant molecule
Most reactions of alkenes examples of
addition reactions
What happens in the addition reaction of alkenes?
One of the two bones in the carbon to carbon double bonds is broken and a new single bond is formed from each of the two carbon atoms.
What happens in the addition of hydrogen to an alkene
When hydrogen gas and an alkene are heated and passed over a finely divided platinum/nickel catalyst the addition reaction produces an alkane
What is hydrogenation?
The addition reaction of alkenes with hydrogen
Give one example when hydrogenation is used
In the manufacture of margarine
What happens in the addition of alkenes to hydrogen halides
When an alkene is through a concentrated solution of hydrogen halide at room temperature the product is halogen alkane
When are 2 possible products possible in the reaction of addition of hydrogen halides?
When there are longer asymmetric alkenes reacting with a hydrogen halide