15.2 Reactions Of Alkanes Flashcards

1
Q

What is the reactivity of alkanes

A

Alkanes are generally unreactive compounds

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2
Q

Why are alkanes generally unreactive

A

There is a very small difference in electronegative between carbon and hydrogen. Therefore they are non-polar, they have no δ+ charge to attract nucleophiles neither do they have areas of high electron density to attract electrophiles.

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3
Q

What are some reactions that alkanes would take place in

A

Alkanes react with oxygen in combustion reactions and also undergo substitution by halogens in sunlight.

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4
Q

Alkanes are often used as fuels for

A

Generating electricity in power stations
To heat our homes and cook our food
To provide energy needed in industrial processes
To provide fuel for vehicles

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5
Q

Chemical equation for combustion of alkanes

A

Alkane+oxygen—>carbon dioxide+ water

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6
Q

What happens when petrol or diesel is burned inside the car engine

A

There is only a limited supply of oxygen. Under these conditions not all the carbon in hydrocarbon fuel is fully oxidised to CO2. Some of the carbon is only partially oxidised to carbon monoxide gas. This is called incomplete combustion.

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7
Q

Why is carbon monoxide harmful

A

It bonds with haemoglobin in your blood. The haemoglobin molecules can then no longer bond to oxygen so cannot transport oxygen around your body.

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8
Q

What will victims of carbon monoxide poisoning fell

A

They will feel dizzy then lose consciousness. If not removed from the toxic gas, the victim will die

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9
Q

What does carbon monoxide smell like

A

It is odourless

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10
Q

Apart from releasing CO, what are some other dangerous gases that car engines release

A

NO and NO2- and other acidic nitrogen oxides.

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11
Q

What are disadvantages of acidic nitrogen oxides being released to the environment

A

They contribute to the problem of acid rains

Acid rains can kill trees and aquatic animals in lakes.
Acid rains erodes limestone buildings and statues
Acid rain corrodes metals such as iron

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12
Q

What causes nitrogen to be oxidised

A

The very high temperatures of car engines

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13
Q

The chemical equation first the production of Nitrogen oxide are

A

N2(g)+O2(g)<—> 2NO(g)
2NO(g)+O2(g)<—>2NO2(g)

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14
Q

What are volatile Organic Compounds (VOCs)

A

Unburnt hydrocarbons released by car engines into the air

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15
Q

What are some harms of VOCs

A

Some of there are carcinogens(can cause cancer)

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16
Q

What are some harms of VOCs

A

Some of them are carcinogens(can cause cancer) and can form PAN, a contributor to photochemical smog

17
Q

What do catalytic converter in exhaust system of car engines do

A

-the oxidation of carbon monoxide to form carbon dioxide
-the reduction of nitrogen oxides to form harmless nitrogen gas
-the oxidation of unburnt hydrocarbons to form carbon dioxide and water

18
Q

What is one problem that catalytic converter cannot solve

A

The emission of carbon dioxide which is a greenhouse gas

19
Q

Chemical equations of reactions taking place inside catalytic converter

A

2CO+2NO—> 2CO2 +N2
2CO+O2—> 2CO2

20
Q

What is the reaction mechanics if substitution reaction in sunlight

A

It is a homolytic reaction therefore it will have initiation step, propagation step and termination steo

21
Q

What in the initiation step in substitution reactions of alkanes

A

The breaking of Cl-Cl bond by energy from ultraviolet light in sunlight

22
Q

What is the propagation step in substitution reactions of alkanes

A

Free radicals are very reactive. They will attack the normal unreactive alkanes.
CH3CH3+Cl•—>•CH2CH3+HCl
•CH2CH3+Cl2–>CH3CH2Cl+Cl•

23
Q

Why is the reaction of substitution reaction of alkanes in sunlight not suitable for getting specific halogenalkanes

A

Because we get a mixture of halogenalkanes for products

24
Q

The more chlorine fas in the reaction mixture to start with, the greater… in substitution reaction of halogens

A

The greater the proportions of chlorine atoms in chloroalkane molecules formed

25
Q

What happens in termination steps in substitution reactions of alkanes

A

When two free radicals meet they will react with each other. A single molecule is the only product. As no free radicals are made that can carry on the reaction sequence, the reaction stops

26
Q

The reaction between alkanes and halogens is called

A

Radical free substitution

27
Q

The reaction between alkanes and halogens is called

A

Radical free substitution