15.2- ETHANOL PRODUCTION Flashcards

1
Q

Why are alcohols very important in industrial chemistry?

A

as they are used as intermediates

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

Why are alcohols used intermediates?

A

easily made + easily converted into other compound

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

What is methanol made from?

A

methane (natural gas)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

What is methanol increasingly being used as?

A

starting material to make other organic chemicals

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

What is by far the most important alcohol?

A

ethanol, C2H5OH

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

What is ethanol used as? (hint- intermediate)

A

intermediate in manufacture of other organic chemicals

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

How is ethanol used in everyday life?

A

solvents in cosmetics, i.e. aftershave + perfume

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

What is ethanol used in the manufacture of? (4)

A

drugs
detergents
inks
coatings

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

How is ethanol industrially made?

A

reacting ethene with stream, using catalyst of phosphoric acid

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

How else is ethanol made?

A

from sugars by fermentation, as in production of alcoholic drinks

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

About how much ethanol does beer have?

A

5%

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

About how much ethanol does wine have?

A

12%

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

About how much ethanol do spirits such as gin + whisky contain?

A

40%

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

How is ethanol concentrated in alcoholic drinks?

A

by distillation

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

How is ethene produced?

A

when crude oil fractions are cracked

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

What is done to ethene to make ethanol?

A

ethene hydrated

17
Q

Equation for making ethanol from ethene

A

CH2=CH2 + H2O -> C2H5OH

phosphoric acid catalyst

18
Q

What happens to carbohydrates during fermentation?

A

carbohydrates from plants broken down into sugars + then converted into ethanol by action of enzymes from yeast

19
Q

Where do the carbohydrates used to make ethanol come from?

A

crops such as sugar cane + sugar beet

20
Q

What is the key step in the breakdown of sugar?

A

anaerobic respiration

21
Q

Equation for making ethanol by fermentation

A

C6H12O6 (aq) -> 2C2H5OH (aq) + 2CO2 (g)

22
Q

What is the rate of anaerobic respiration affected by?

A

affected by temperature

23
Q

At what temperature is anaerobic respiration slow?

A

low temperatures

24
Q

Why should the temperature not be too high during anaerobic respiration?

A

enzymes made ineffective

25
What is the compromise temperature used for anaerobic respiration? (making ethanol by fermentation)
35°C- little below our body temperature
26
Why is air kept out of the fermentation vessels? (making ethanol by fermentation)
prevent oxidation of ethanol to ethanoic acid (acid in vinegar)
27
What happens once the fermenting solution contains about 15% ethanol?
enzymes unable to function + fermentation stops
28
How can the ethanol be removed from the mixture after the fermentation stops? (making ethanol by fermentation)
ethanol may be distilled from mixture by fractional distillation as its boiling temp (78°C) less than water (100°C)
29
What is the rate of reaction like for cracking and hydration? (ethanol production)
fast
30
What is the rate of reaction for fermentation + distillation like? (ethanol production)
slow
31
What type of process is cracking + hydration? (ethanol production)
continuous
32
What types of process is fermentation + distillation? (ethanol production)
batch
33
What is the purity like when ethanol is produced from cracking + hydration?
essentially pure
34
What is the purity like when ethanol is produced from fermentation + distillation?
aqueous solution of ethanol produced
35
Why is ethene a vital industrial chemical?
starting material for poly(ethene) + many other important chemicals
36
How can ethene be produced from ethanol?
dehydrating ethanol made from sugar, giving renewable source of ethene
37
At present how Is ethene made?
from crude oil + then converted into ethanol
38
What is a more economical way to produce ethene?
from ethanol made by fermenatation