1.5 Kinetics Flashcards

1
Q

What is collision theory?

A

A reaction won’t take place between two particles unless they collide in the right direction and collide with at least a certain amount of kinetic energy.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

What is activation energy?

A

The minimum amount of energy required for a reaction to occur.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

Name the graph that represents the different amounts of kinetic energy in molecules.

A

Maxwell-Boltzmann graph

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

What does a Maxwell-Boltzmann graph show?

A

The different kinetic energies of molecules in a gas.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

Label the x-axis and y-axis of a Maxwell-Boltzmann graph.

A

X-axis: amount of kinetic energy
Y-axis: number of molecules

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Where does the curve of a Maxwell-Boltzmann start? Why?

A

(0,0)
Because no molecules have 0 energy.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

What does the peak of a Maxwell-Boltzmann represent?

A

The most probable energy (mode)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

Where can you find the mean of the curve?

A

Just to the right of the peak of the curve.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

Where is the activation energy found on the Maxwell-Boltzmann graph?

A

Towards the RHS when the curve starts to slowly lower.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

What is the area under the curve of a Maxwell-Boltzmann graph?

A

The total number of molecules.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

What happens when you increase temperature of a gas?

A

Molecules will have more kinetic energy so it’s probable that more successful collisions occur. Hence a greater proportion of molecules will have at least the activation energy to react.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

How does an increase in temperature affect a Maxwell-Boltzmann graph?

A

The curve will be pushed more to the right and its peak lowers as the number of molecules remain the same. Hence the area under curve doesn’t change.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

What happens when you increase concentration of a gas?

A

The molecules will be closer together and more successful collisions are likely to happen. Hence a greater proportion of molecules will have at least the activation energy to react.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

How does an increase in concentration affect a Maxwell-Boltmann graph?

A

The curve peak would be higher.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

What happens when you increase the pressure of a gas?

A

Molecules will be more tightly packed and closer together so more successful collisions are likely to happen. Hence a greater proportion of molecules will have at least the activation energy to react.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

What is a catalyst?

A

A substance that increases the rate of a reaction by providing an alternative pathway with a lower activation energy. The catalyst is chemically unchanged at the end of a reaction.

17
Q

Why are catalysts used during industrial processes?

A

It’s cheap, can be reused, saves money on high temperatures, high pressure etc.

18
Q

How does a catalyst affect an enthalpy diagram?

A

Activation energy lowers so peak lowers.

19
Q

How does a catalyst affect a Maxwell-Boltzmann graph?

A

The peak remains unchanged.
The activation energy will move more to the left.

20
Q

What does uncatalysed mean?

A

A reaction that doesn’t have a catalyst.

21
Q

What is a main difference in terms of energy distribution between using a catalyst or raising temperature?

A

Raising temperature changes the energy distribution.
Catalyst does not affect energy distribution so it remains the same.

22
Q

What is rate of reaction?

A

The change in the amount of reactant/product over time.

23
Q

How do you calculate rate of reaction?

A

Amount of reactant used or product formed / time

24
Q

What are the units for rate of reaction?

A

volume or mass/time
e.g. cm3 s-1 or g s-1

25
Q

What methods can you use to measure rate of reaction?

A

Time taken for a precipitate to form, change in mass over time, volume of gas produced over time.

26
Q

Outline a method for the time taken for a precipitate to form.

A

-Place a conical flaks on a white tile with a black cross
-Mix reactants together and start timer
-Stop the timer once precipitate has formed and the cross is no longer visible

27
Q

Outline a method for the time taken for a permanent mass change.

A

-Place a conical flask on a balance and set to 0
-Mix reactants in flask and record initial mass and start timer
-Read off mass at regular intervals
-Stop timer once mass remains constant

28
Q

Outline a method for the time taken for volume of gas to be produced.

A

-Mix reactants in a conical flask
-Attach a Bung and gas syringe to conical flask and start timer
-Read off volume produced at regular intervals
-Stop timer once volume of gas remains constant