12.12 - Hydrogen Ion Concentration and the pH Scale Flashcards

1
Q

What do strong acids do in solution?

A

Fully dissociate

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2
Q

What does this mean for the concentration of hydrogen ions after a strong acid has dissociated?

A

It is equal to the initial concentration of the acid

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3
Q

What equation links the pH of an aqueous solution and its hydrogen ion concentration?

A

pH = -log[H+]

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4
Q

What is [H+] measured in?

A

mol dm-3

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5
Q

When rearranged for [H+], what does the equation state?

A

[H+] = 10^(-pH)

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6
Q

Why is calculating [H+] more difficult for weak acids?

A

They don’t fully dissociate

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7
Q

What new value helps to calculate [H+] for a weak acid?

A

Ka, the acid dissociation constant

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8
Q

For a weak acid with chemical formula HA, what is the expression for Ka?

A

([H+][A-])/[HA]

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9
Q

What is the chemical equation for the dissociation of HA in aqueous solution?

A

HA H+ + A-

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10
Q

What does this equation tell you about [H+] and [A-}?

A

They are equal

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11
Q

Why?

A

Because they have a 1:1 ratio in the reaction

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12
Q

What does this simplify the Ka expression to?

A

Ka = [H+]^2/[HA]

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13
Q

If Ka is a small number, what is a reasonable assumption to make?

A

The concentration of HA at equilibrium is the same as the initial concentration of HA

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14
Q

What equation links pKa and Ka?

A

pKa = -logKa

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