12.12 - Hydrogen Ion Concentration and the pH Scale Flashcards
What do strong acids do in solution?
Fully dissociate
What does this mean for the concentration of hydrogen ions after a strong acid has dissociated?
It is equal to the initial concentration of the acid
What equation links the pH of an aqueous solution and its hydrogen ion concentration?
pH = -log[H+]
What is [H+] measured in?
mol dm-3
When rearranged for [H+], what does the equation state?
[H+] = 10^(-pH)
Why is calculating [H+] more difficult for weak acids?
They don’t fully dissociate
What new value helps to calculate [H+] for a weak acid?
Ka, the acid dissociation constant
For a weak acid with chemical formula HA, what is the expression for Ka?
([H+][A-])/[HA]
What is the chemical equation for the dissociation of HA in aqueous solution?
HA H+ + A-
What does this equation tell you about [H+] and [A-}?
They are equal
Why?
Because they have a 1:1 ratio in the reaction
What does this simplify the Ka expression to?
Ka = [H+]^2/[HA]
If Ka is a small number, what is a reasonable assumption to make?
The concentration of HA at equilibrium is the same as the initial concentration of HA
What equation links pKa and Ka?
pKa = -logKa