10C- calculating pH-Table 1 Flashcards

1
Q

Define
acidic solution

A

Solution containing a greater concentration of hydronium ions than hydroxide ions

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2
Q

Define
basic solution

A

Solution containing a greater concentration of hydroxide ions than hydronium ions

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3
Q

Define
neutral solution

A

Solution containing an equal concentration of hydronium and hydroxide ions

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4
Q

Define
autoionization

A

Process by which an atom or molecule spontaneously forms ions

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5
Q

Define
ionic product of water (Kw)

A

Expression of the concentration of ions present in water at 25 °C

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6
Q

Define
pH

A

Measure of the concentration of hydronium ions in a solution

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7
Q

Define
pH scale

A

pH values arranged on a logarithmic scale

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8
Q

Ionic(n.) product
definition

A

-Ionic product(n.)=The product of
concentrations of ionic species

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9
Q

Ionisation(v.)
definition

A

-Ionisation(v.)=Conversion of substance into
ions.

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10
Q

Acidity definition

A

-Acidity(adj.)=level of acid in a substance

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11
Q

what happens when water is ionised

A

H2O(l) + H2O(l) H3O+(aq) + OH−(aq)
water acts as a weak acid and weak base

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12
Q

list some monoprotic acids

A

hydrochloric acid (HCl), ammonium (NH4), nitric acid (HNO3), ethanoic acid (CH3COOH)
HANE (hydrochloric acid, ammonium, nitric acid, ethanoic acid)

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13
Q

define monoprotic

A

species that can only donate one proton, H+, during ionisation

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14
Q

list some diprotic acids

A

sulfuric acid (H2SO4), carbonic acid (H2CO3), hydrogen sulfide (H2S), selenous acid (H2SeO3)
SCHS ( sulfuric acid, carbonic acid, hydrogen sulfide, selenous acid)

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15
Q

define diprotic

A

species that can donate up to two protons, H+, during ionisation

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16
Q

list some triprotic acids

A

phosphoric acid (H3PO4), citric acid (C6H8O7), arsenic acid (H3AsO4), boric acid (H3BO3)
PCAB

17
Q

define triprotic

A

species that can donate up to three protons, H+, during ionisation

18
Q

list some amphiprotic acids

A

water (H2O), hydrogen sulfate ( HSO4(-)),hydrogen carbonate (HCO3(-)), di hydrogen phosphate (H2PO4(-)), hydrogen phosphate ( HPO4(2-))

19
Q

define amphiprotic

A

species that can either donate or accept a proton, H+

20
Q

define pH

A

measure of the concentration of hydronium ions in a solution

21
Q

kW formula (aka ionic product formula)

A

Kw = [H3O+] × [OH−]
Kw = (1.00 × 10−7 M) × (1.00 × 10−7 M)
Kw = 1.00 × 10^−14 M2

22
Q

pH formula

A

pH = −log10[H3O+]

23
Q

what is kW

A

the ionic product of water: expression of the concentration of ions present in water at 25°C

Kw is always equal to 1.00 ⨉ 10-14 M^2 at 25°C

This formula only valid at 25 degrees Celsius

24
Q

If neutral pH is still defined as when [H3O+] = [OH–], what would be considered neutral pH at 100°C, assumingKwis equal to 51.3 × 10–14M2?

A

H3O x OH = 51.3 x 10^-14
H3O=OH
H3O x H3O = 51.3 x 10^-14
H3O= √51.3 x 10^-14
H3O= 7.162 x 10^-7
pH= -log 10 (7.16 x 10^-7)
pH=6.14

25
Acid solutions ratio of H3O+ and OH- concentration
pH 7 < [H3O+] >1.0 × 10−7 M and [OH−] < 1.0 × 10−7M
26
Neutral solutions ratio of H3O+ and OH- concentration
pH = 7, [H3O+] = [OH−] = 1.0 × 10−7 M
27
basic solutions ratio of H3O+ and OH- concentration
pH 7 >[H3O+] <1.0 × 10−7 M and [OH−] >1.0 × 10−7M
28
how to calculate pH
pH = −log10[H3O+]
29
how to calculate H3O concentration
[H3O+] = 10^−pH
30
what factor is pH change
every increase or decrease in pH by 1 means that there was a change in the concentration of H3O by a factor of 10
31
Calculate the pH of a 0.30 M solution of hydrochloric acid at 25 .
[HCl] = [H3O+] = 0.30 M pH = −log10[H3O+] pH = −log10 (0.30 M) pH = 0.52
32
Explain the autoionisation of water.
-Pure water undergoes a tiny degree of ionisation with itself -This is possible due to water's amphiprotic nature   H2O(l){acid} + H2O(l){Base}⇌ H3O^(+)(aq) + OH^(-)   -There will be very low concentrations of product as only a small amount of this reaction will occur due to the strenght of the acid and base being low.
33
What does pH stand for(not necessary but fun)
What does pH stand for?=Potenz of hydrogen=power of hydrogen= -p=power=originates from the german word potenz -H=hydrogen
34
What is the pH scales and what does it do
-measurement of acidity= simplified further using measurement of pH -pH scale= measurement of acidity of a solution on a scale of 0-14(this only valid at 25 degrees Celsius )