10 - Sour Water Corrosion (Acidic) Flashcards
Corrosion of steel due to acidic sour water containing H2S at a pH between ,,,,,,,. Carbon
dioxide (CO2) may also be present.
Sour Water Corrosion (Acidic) or SWC
4.5 and 7.0
The H2S concentration in the sour water is dependent on the ,,,,,,,, in the gas phaseas well as ,,,,
H2S partial pressure
temperature and pH.
At a given pressure, the H2S concentration in the sour water ,,,,,,,,, as temperature increases.
decreases
Increasing concentrations of H2S tend to decrease solution pH down to about ,,,,,,
4.5
Streams with a pH below ,,,, indicate the presence of a strong acid which would be the main corrosion concern
4.5
Above a pH of about ,,,,,, a protective, thin iron sulfide layer limits the corrosion rate
4.5,
contaminants of HCl and CO2 lower ,,,,,,,
pH (more acidic).
Ammonia significantly increases ,,,,, and is more often associated with ,,,,,,,,,, where the main concern is ,,,,,,,,, corrosion
pH
alkaline sour water
ammonia bisulfide
300 Series SS can be used at temperatures below about ,,,,,, where Chloride Stress Corrosion Cracking (CSCC) is not likely
140oF