1. The Particulate Nature of Matter Flashcards

1
Q

Describe the attractive forces in solids

A

Strong forces of attraction between particles, particles are packed very closely together in a fixed and regular pattern

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2
Q

Describe the attractive forces in liquids

A

Weaker attractive forces in liquids than in solids, particles are close together in an irregular, unfixed pattern

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3
Q

Describe the attractive forces in gases

A

No intermolecular forces, particles are in random movement and so there is no defined pattern

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4
Q

Describe the movement in solids

A

Atoms vibrate in position but can’t change position or move

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5
Q

Describe the movement in liquids

A

Particles can move and slide past each other which is why liquids adopt the shape of the container they’re in and also why they are able to flow

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6
Q

Describe the movement in gases

A

Particles are far apart and move quickly (around 500 m/s) in all directions, they collide with each other and with the sides of the container (this is how pressure is created inside a can of gas)

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7
Q

Describe the fixed volume and density in solids

A

solids have a fixed volume, shape and high density

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8
Q

Describe the fixed volume and density in liquids

A

Liquids have a fixed volume but not a fixed shape and have a moderate to high density

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9
Q

Describe the fixed volume and density in gases

A

No fixed volume, since there is a lot of space between the particles, gases can be compressed into a much smaller volume. Gases have low density

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10
Q

What change occurs during melting?

A

Melting is when a solid changes into a liquid

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11
Q

What does melting require?

A

Requires heat energy which transforms into kinetic energy, allowing the particles to move

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12
Q

When does melting occur?

A

Occurs at a specific temperature known as the melting point (m.p.) which is unique to each pure solid

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13
Q

What change occurs during boiling?

A

Boiling is when a liquid changes into a gas

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14
Q

What does boiling require?

A

Requires heat which causes bubbles of gas to form below the surface of a liquid, allowing for liquid particles to escape from the surface and within the liquid

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15
Q

When does boiling occur?

A

Occurs at a specific temperature known as the boiling point (b.p.) which is unique to each pure liquid

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16
Q

What change occurs during freezing?

A

Freezing is when a liquid changes into a solid

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17
Q

When does freezing occur?

A

This is the reverse of melting and occurs at exactly the same temperature as melting, hence the melting point and freezing point of a pure substance are the same. Water for example freezes and melts at 0ºC

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18
Q

What does freezing require?

A

Requires a significant decrease in temperature (or loss of thermal energy) and occurs at a specific temperature which is unique for each pure substance

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19
Q

What change occurs during evaporation?

A

When a liquid changes into a gas.

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20
Q

What is the difference between boiling and evaporation?

A

Evaporation occurs only at the surface of liquids where high energy particles can escape from the liquid’s surface at low temperatures, below the b.p. of the liquid

21
Q

What increases the rate of evaporation?

A

The larger the surface area and the warmer the liquid/surface, the more quickly a liquid can evaporate

22
Q

What is required for evaporation? (if anything)

A

No energy is required for evaporation to occur and it takes place over a range of temperatures

23
Q

What change occurs during condensation?

A

When a gas changes into a liquid, usually on cooling

24
Q

How does condensation occur (in terms of particles)?

A

When a gas is cooled its particles lose energy and when they bump into each other they lack the energy to bounce away again, instead they group together to form a liquid

25
Q

What is required for condensation? (if anything)

A

No energy is required for condensation to occur and it takes place over a range of temperatures

26
Q

What change occurs during sublimation?

A

When a solid changes directly into a gas

27
Q

What example of solids can undergo sublimation?

A

This happens to only a few solids such as iodine or solid carbon dioxide

28
Q

What is the reverse reaction of sublimation?

A

The reverse reaction also happens and is also called sublimation (sometimes called deposition or desublimation)

29
Q

When does sublimation occurr?

A

Sublimation occurs at a specific temperature which is unique for a pure substance

30
Q

In what type of motion are gaseous particles in?

A

Gaseous particles are in constant and random motion

31
Q

What happens to gaseous particles when there is an increase in temperature?

A

An increase in temperature increases the kinetic energy of each particle, as the thermal energy is transformed to kinetic energy, so they move faster

32
Q

What causes pressure in a container?

A

The pressure that a gas creates inside a closed container is produced by the gaseous particles hitting the inside walls of the container.

33
Q

What is the effect of increasing temperature on pressure?

A
  • As the temperature increases, the particles in the gas move faster, impacting the container’s walls more frequently
  • Therefore an increase in temperature causes an increase in pressure
34
Q

Brownian Motion definition

A

Brownian motion is defined as the random movement of particles in a liquid or a gas produced by large numbers of collisions with smaller, often invisible particles

35
Q

What does the observation of brownian motion prove?

A

the correctness of the kinetic particle theory

36
Q

Diffusion definition

A

This is the process by which different gases or different liquids mix and is due to the random motion of their particles

37
Q

From where to where do diffusing particles move?

A

Diffusing particles move from an area of high concentration to an area of low concentration, till the concentration of particles is even

38
Q

Does diffusion require energy?

A

NO

Diffusion happens on its own and no energy input is required although it occurs faster at higher temperatures

39
Q

What is the basis of the kinetic theory of matter?

A

When substances are heated, the particles absorb thermal energy which is converted into kinetic energy

40
Q

What happens when you heat a solid?

A

Heating a solid causes its particles to vibrate more and as the temperature increases, they vibrate so much that the solid expands until the structure breaks and the solid melts

41
Q

What happens when you heat a liquid?

A

On further heating, the now liquid substance expands more and some particles at the surface gain sufficient energy to overcome the intermolecular forces and evaporate

42
Q

What happens when the b.p. temperature is reached in a liquid?

A

When the b.p. temperature is reached, all the particles gain enough energy to escape and the liquids boils

43
Q

What type of graph can be used to show how changes in temperature affect changes in state?

A

A heating curve - solid to gas

A cooling curve - gas tp solid

44
Q

What is an example of Brownian Motion?

A

An example of Brownian motion is the observed jerky and erratic motion of smoke particles as they are hit by the unseen molecules in the air which can be seen under a microscope

45
Q

What is the basic condition needed to show the Brownian process is occurring?

A

In all cases, larger and visible particles are caused to move by the random bombardment of smaller, invisible particles

46
Q

In what state does diffusion happen the fastest?

A

Diffusion occurs much faster in gases than in liquids as gaseous particles move much quicker than liquid particles

47
Q

Do gases diffuse at different rates at the same temperature?

A

YES

- At the same temperature, different gases do not diffuse at the same rate.

48
Q

What causes the difference in the rate of diffusion in gases?

A

This is due to the difference in their relative molecular masses

49
Q

At what relative molecular mass do gas particles diffuse the fastest?

A

Lighter gas particles can travel faster and hence further, therefore the lower its relative mass the faster a gas will diffuse