1 Organic Chemistry Flashcards

1
Q

organic compound

A

is defined as a carbon containing compound that does
not include CO,CO2, and HCN
➢ These compounds are found and obtained from living things
➢ often molecular compounds with low boiling points
➢ ex) Hydrocarbons and fuels such as fats and oils

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

Inorganic compounds

A

are compounds obtained from non-living sources
➢ CO, CO2,and HCN are inorganic compounds that contain carbon

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

alkanes

A

Saturated Hydrocarbons, non polar, fairly unreactive but combustable

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Alkenes

A

The unsaturated hydrocarbons with double bond

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

Alkynes

A

The unsaturated hydrocarbons with triple bond

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Aromatic hydrocarbons

A

classified on presence of a benzene ring, unsaturated hydrocarbon, bonding arrangement makes it chemically stable

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

Properties of Alkanes

A

nonpolar molecules, as there is an even arrangement of C-H bonds
throughout the molecule
ΔEN of the C-H bond is quite low and is almost nonpolar as is, while the C-C bonds are truly nonpolar
- intermolecular forces very low, relies more on London Dispersion Forces
- fairly unreactive, but are combustible

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

alkyl group

A

one or more carbon atom that forms a branch off the main chain of hydrocarbon

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

substituent group

A

an atom or group that replaces a hydrogen atom in an organic compound

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

Alcohols

A

organic compounds that contain a hydroxyl group (R-OH)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

Properties of Alcohols

A

alcohols partially polar.
hydrogen bonding with other hydroxyl groups,
alcohols have greater boiling points
than alkanes, and can also dissolve into water,
alcohols with short carbon chains are more soluble in water than those with longer chains, as
the longer the carbon chain grows the less polar it is

❖ ability to be a solvent for both polar and nonpolar molecules, as the saturated hydrocarbon is nonpolar and the hydroxyl group is polar

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

hydration reaction

A

reaction involves an alkene and a water molecule

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Dehydration

A

is the reverse of an addition reaction, where a water
molecule is produced but requires a catalyst to do so

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

ethers

A

product of a condensation reaction between two alcohols, Ethers are useful solvents, as they have a very polar C-O bond, and can
also dissolve nonpolar substances due to the alkyl groups

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

thiols

A

organic compounds that contain the sulfhydryl functional group
(-SH),
SH works similar to a hydroxil group becuase they have similar configurations
A property of thiols is that of smelly and strong odours (sulfur)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

carbonyl group

A

a functional group in which a carbon is double bonded
to an oxygen atom

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
17
Q

Aldehydes

A

have a carbonyl group that is bonded to at least one hydrogen atom,they have disticnt scent and odour due to carbonyl group, have dipole dipole interactiions but are less polar than alchols (since they cant form hydrogen bonds), are produced from primary alchols

18
Q

Ketones

A

have a carbonyl group that is bonded to at least two carbon atoms on
each side of the carbonyl group

19
Q

formation of aldehydes and ketones

A

For aldehydes and ketones to be synthesized, an alcohol must go through
controlled oxidation

20
Q

Hydrogenation reactions

A

involve the addition of a H2
molecule to another
molecule

21
Q

esters

A

formed by the condensation reaction between an alcohol and a carboxylic acid

22
Q

properties of esters

A

Polarity of esters is similar to that of aldehydes and ketones as esters lack the hydroxyl group
The presence of oxygen atoms does still mean that esters have strong dipole-dipole interactions and therefore larger chains form waxy solids at room temperature but shorter chains are gases at room temperature
Less polar than carboxylic acids

23
Q

Formation of carboxylic acids

A

is the result of further controlled oxidation of an aldehyde

24
Q

Esterification

A

the condensation reaction in which an ester is formed from an alcohol and carboxylic acid

25
Q

Reversing Esterification

A

When esters are treated with an acid or a base, the esterification process can be reversed through hydrolysis

26
Q

saturated fats

A

form solids at room temperature as the tails are tightly packed while

27
Q

unsaturated fats

A

unsaturated fats are liquids at room temperature

28
Q

saponification

A

process of making soap by heating fats or oils with a strong base

29
Q

Trans fats

A

re o not able to be completely digested or broken down by the body, and have become a topic of nutritional health

30
Q

lipid

A

class of organicc compound that includes fats and oils

31
Q

fatty acid

A

long chain carboxylix acid

32
Q

triglyceride

A

an ester formed rom long-chain fatty acids and glycerol

33
Q

Amines

A

nitrogen based functional groups, with one or more hydrogen
atoms possibly replaced by alkyl groups

34
Q

properties of amines

A

strong smell, which is due to the fact that it is a
derivative of ammonia

❖ Amines are very polar, as the N-C and N-H always has an EN difference towards
the nitrogen in the bond
➢ bp and mp increase

35
Q

functional group

A

a group of atoms within a molecule that determines the properties of the molecule such as solubility, polarity, melting point, boiling point, and chemical
reactivity.

36
Q

halogenation

A

halogen is added to the hydrocarbon and reokaces multibond

37
Q

Markovnikovʼs Rule

A

The hydrogen atom will bond with the carbon with the
most hydrogen atoms already bonded to it

38
Q

properties of aromatic hydrocarbons

A

state at room temp depends on functional group, symmetrical strucutre makes them non-polar, unless a substituent is electronegative

39
Q

substitution reaction

A

characteristic of saturated hydrocarbons,where a hydrogen on a carbon is substituted with a functional
group (in benzene this requires a catalyst or heat as bonds are more stable)

40
Q

controlled oxidation

A

the reactant alcohol is not completely oxidized due to oxygen being the limiting reagent or of limited quantity

41
Q

property of carboxylic acid

A

high melting points (much higher than alknes), highly polar, smaller chains are very soluable in water, carboxyl group provides strong dipole dipole interaction

42
Q

esterfication

A

the condensation reaction in which an ester is formed from an alcohol and carboxylic acid