1. enthalpy changes Flashcards

1
Q

Enthalpy change delta H

A

is the heat energy transferred in a reaction at constant pressure

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2
Q

what are the units of enthalpy change (delta H)

A

kJmol-1

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3
Q

delta H theta means

A

measurements made under standard conditions and elements were in their standard states

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4
Q

what are standard conditions

A

100 kPa

298 K

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5
Q

exothermic reactions

  1. what do they do concerning energy
  2. is delta H + or -
A
  1. give out energy

2. negative

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6
Q

exothermic

  1. what reaction is usually exothermic
  2. examples
A
  1. oxidation
  2. combustion of a fuel like methane.
    CH4(g) + 2O2(g) -> CO2(g) + 2H2O(l)
    oxidation of carbs such as glucose in respiration
    C6H12O6
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7
Q

endothermic reactions

  1. what do they do concerning energy
  2. is delta H + or -
A
  1. absorb energy

2. positive

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8
Q

endothermic

2 e.g. of endothermic reaction

A
  1. thermal decoposition of calcium carbonate
    CaCO3(s) -> CaO(s) + CO2(g)
  2. main reactions of photosynthesis (sunlight supplies energy
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9
Q

what do enthalpy profile diagrams show

A

how enthalpy (energy) changes during reactions

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10
Q

what is the activation energy Ea

A

the minimum amount of energy needed to begin breaking reactants bonds and start a chemical reaction

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11
Q

2 ways of finding enthalpy change

A

experiment

data books

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12
Q

enthalpy are affected by _____

so it is important to measure enthalpy under _____

A

temperature and pressure

standard conditions

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13
Q

definition

standard enthalpy change of reaction (delta r H theta)

A

enthalpy change
when the reaction occurs in the molar quantities
shown in the chemical equation
under standard conditions

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14
Q

definition

standard enthalpy change of formation (delta f H theta)

A
enthalpy change 
when 1 mole of a compound is formed 
from its elements 
in their standard states 
under standard conditions
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15
Q

definition

standard enthalpy change of combustion (delta c H theta)

A

enthalpy change
when 1 mole of a substance
is completely burned in oxygen
under standard conditions

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16
Q

definition

standard enthalpy change of neutralisation (delta neut H theta)

A

enthalpy change
when an acid and an alkali react together
under standard conditions
to form 1 mole of water