1. enthalpy changes Flashcards
Enthalpy change delta H
is the heat energy transferred in a reaction at constant pressure
what are the units of enthalpy change (delta H)
kJmol-1
delta H theta means
measurements made under standard conditions and elements were in their standard states
what are standard conditions
100 kPa
298 K
exothermic reactions
- what do they do concerning energy
- is delta H + or -
- give out energy
2. negative
exothermic
- what reaction is usually exothermic
- examples
- oxidation
- combustion of a fuel like methane.
CH4(g) + 2O2(g) -> CO2(g) + 2H2O(l)
oxidation of carbs such as glucose in respiration
C6H12O6
endothermic reactions
- what do they do concerning energy
- is delta H + or -
- absorb energy
2. positive
endothermic
2 e.g. of endothermic reaction
- thermal decoposition of calcium carbonate
CaCO3(s) -> CaO(s) + CO2(g) - main reactions of photosynthesis (sunlight supplies energy
what do enthalpy profile diagrams show
how enthalpy (energy) changes during reactions
what is the activation energy Ea
the minimum amount of energy needed to begin breaking reactants bonds and start a chemical reaction
2 ways of finding enthalpy change
experiment
data books
enthalpy are affected by _____
so it is important to measure enthalpy under _____
temperature and pressure
standard conditions
definition
standard enthalpy change of reaction (delta r H theta)
enthalpy change
when the reaction occurs in the molar quantities
shown in the chemical equation
under standard conditions
definition
standard enthalpy change of formation (delta f H theta)
enthalpy change when 1 mole of a compound is formed from its elements in their standard states under standard conditions
definition
standard enthalpy change of combustion (delta c H theta)
enthalpy change
when 1 mole of a substance
is completely burned in oxygen
under standard conditions