02 Hydrogen Atom Flashcards

1
Q

What is a line spectrum

A

a spectrum showing only certain colors of light

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2
Q

spectrum for white light

A

contains all frequencies of visible light

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3
Q

what is a lazer

A

monocromatic spectrum

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4
Q

absorption

A

ground state -> excited state

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5
Q

emission

A

excited state -> ground state

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6
Q

electronic transition

A

an electron within an atom is jumping from one allowed state to another and emitting a photon in the form of electromagnetic radiation

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7
Q

as n decreases…

A

distance decreases, attraction increases and energy gets lower or more negative

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8
Q

is attractive energy more negative or more positive

A

more negative

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9
Q

electron transitions from a higher (less negative) energy orbit (larger n) to a lower (more negative) orbit result in…

A

the emission of photons with matching energies

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10
Q

absorption of photons of the appropriate energy…

A

promotes electrons from a lower orbit to a higher one

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11
Q

at n = infinity, energy is

A

zero

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12
Q

what is ionization

A

atom gaining or losing electrons to form ions

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13
Q

energy will be negative when we have _______ and indicates a ________

A

an attractive interaction
a release of energy

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14
Q

closer to the nucleus =
higher or lower energy

A

lower energy
- due to the significant attractive forces

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15
Q

both disance and energy are…

A

quantized! meaning that only specific values are possible

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16
Q

as n increases…

A

the radius increases
the energy will increase and will become less negative
the energy levels get closer and closer together

17
Q

what is electron density

A

the probability of an electron residing in a given tiny volume of space

18
Q

what is ionization energy

A

energy needed to remove an electron

19
Q

what does being quantized mean

A

can only have specific values

20
Q

what is an orbital

A

a 3d region of space that can hold an electron

21
Q

where is electron density the highest

A

around the nucleus, tapers off as you get farther

22
Q

what are quantum numbers

A

numbers required to describe arrangement of electrons in an atom

23
Q

Principal quantum number (n)

A

tells us the shell
indicates energy and distance from the nucleus
integer ranging from 1 to infinity
(city)

24
Q

angular momentum quantum number (l)

A

integer ranging from 0 to n-1

25
Q

what letter is l = 0
and what shape does this correspond to

A

s (sphere)

26
Q

what letter and shape does l = 1 correspond to

A

p and ‘dumbells’

27
Q

what letter and shape does l = 2 correspond to

A

d and ‘clover’ or ‘dumbell donut’

28
Q

what letter and shape does l = 3 correspond too

A

f and the shape is too complicated to define

29
Q

what is magnetic quantum number (ml)

A

integer ranging from -l … 0 … +l
the number of possible ml gives the number of orbitals in the subshell
describes spatial oreintation

30
Q

what does degenerate mean

A

having an equal energy

31
Q

what is boundary surface

A

the surface within which there is a specified probability (often 90%) that an electron will be found

32
Q

what is energy splitting due to

A

it is due to electron-electron repulsion and the idea of effective nuclear charge

33
Q

what are the only two values that the magnetic momentum of an electron can be

A

+1/2 or -1/2

34
Q

n

A

o