错题 Flashcards

1
Q

Why is major organic product more stable than minor

A

It has a greater number of alkyl group bonded to the C showing largest inductive effect.

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2
Q

why does N2 not behave as an ideal gas at very high pressure

A

Particles are forced to be together therefore increased intermolecular force. Molecule’s volume will no longer be negligible

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3
Q

Why does lithium sulfide have a high melting point( explain in terms of the structure)

A

It has a giant structure which there will be many strong ionic bonds

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4
Q

A sample of BaBr2 is dissolved in water. Chlorine gas is then bubbled into the solution .
Describe the observations for this reaction:

A

Solution will turn from colorless to brown due to bromine.

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5
Q

Predict the effect of using 2-chloro-2-methylpropane compared to 2-bromo-2-methylpropane on the time taken for the pink colour to disappear. Explain your answer

A
  • Chlorine is a bad leaving group as it has a smaller atomic radius than bromine. This means that chlorine has a higher electron density which makes it a stronger base than bromine as it will attract protons easier. This will cause the pink color to take longer to disappear
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6
Q

Name two physical property typical of ceramic materials

A

Strong
High melting points

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7
Q

SiCl4 + H2O
Observations:

A

SiCl₄ + 2H₂O → SiO₂ + 4HCl
Misty fumes + white solid (SiO₂)

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8
Q

Which two group 2 compounds can produce gas when heated and what gases are produced

A

Metal Carbonates - CO2
Metal Nitrates - NO2 + O2

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9
Q

Difference between elimination and oxidation reaction

A

Elimination removes an hydrogen AND a group (e.g. OH)
Oxidation only removes hydrogen from the compound

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10
Q

In nucleophilic substitution, does bromoalkane react faster or iodoalkane

A

Iodoalkane as it has a longer bond length therefore the bond is very weak, so faster reaction will happen.

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