YIELD AND ATOM ECONOMY Flashcards
Why may the mass of a reaction product may be less than the maximum possible?
- The reaction is reversible & so may not be complete
- There are side-reactions that lead to other products that are not wanted
- The product may need to be purified, which may result in loss of product.
What is theoretical yield?
The maximum possible mass of a product, assuming complete reaction and no losses.
How do you calculate the percentage yield?
actual yield/theoretical yield x 100
What is the actual yield?
The actual mass obtained.
How do you calculate theoretical yield?
Step 1: Calculate the amount of starting material
Step 2: Use the reaction ratio to calculate the amount of desired product.
Step 3: Calculate mass of desired product
1kg = …g
1 x 10³
What is the definition of atom economy?
The molar mass of the desired product divided by the sum of the molar masses of all the products, expressed as a percentage.
What other factors affect the suitability of an industrial process?
- Scarcity of non-renewable raw materials
- The cost of raw materials
- The quantity of energy needed.
What is the expression used to calculate atom economy?
molar mass of the desired product/sum of the molar masses of all products x 100
Addition reactions have…
100% atom economy.
Elimination and substitution reactions have…
lower atom economies.