X-ray diffraction by crystals, Types of crystals and Amorphous solids Flashcards
refers to the scattering of X-rays by the units of a crystalline solid. The patterns produced by scattering or diffraction are used to deduce the
particle arrangement in the solid lattice.
X-ray diffraction
basically tells us the relative electron densities at various locations in a molecule.
electron-density contour map
TYPES OF CRYSTALS
The classification of
any crystal has four types: ionic, covalent, molecular or metallic.
There are two important characteristics of ionic crystals and they
are as follows:
(1) They are composed of charged species and
(2) anions and cations are generally quite different in size.
The_______of the ions must be known because it is helpful in
understanding the structure and stability of these compounds.
radii
Covalent crystals exists when atoms are held together in an
extensive three-dimensional network by covalent bonds. Examples
are the two allotropes of carbon: diamond and graphite.
COVALENT CRYSTALS
is considered as a good conductor of electricity in
directions along the planes of carbon atoms. This is because
electrons are free to move around in this extensively delocalized
molecular orbital.
Graphite
MOLECULAR CRYSTALS
The lattice points in a molecular crystal are occupied by
molecules which has van der Waals forces and/or hydrogen
bonding.
The molecules in a ________ (except for ice) are packed
together as closely as their size and shape allow.
molecular crystals