wording Flashcards

1
Q

Trends Structure

A

Define factor
state the trend
what is happening to # of p and nuclear charge
where are e going
what does this mean for sheilding and dist from nucleus
what does this mean for factor

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2
Q

Atomic Radii decreases

A

across the period

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3
Q

Atomic increases

A

down a group

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4
Q

electron are added to same shell

A

across a period

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5
Q

e are added to new shells

A

down a period

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6
Q

Electronegativity (def)

A

the measure of attraction between a nucleus and a bonding pair of e

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7
Q

Electrongativity increases

A

across a period (left to right)

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8
Q

Electronegativity decreases

A

down a group

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9
Q

Atomic Radii (def)

A

total distance from the nucleus of an atom to the outermost orbital of its electron

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10
Q

1st Ionisation energy (def)

A

the energy required to remove the least tightly bound electron from a mole of atoms in the gaseous state

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11
Q

High Ionisation energy

A

takes a lot of energy to remove the outermost e

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12
Q

Low Ionisation energy

A

takes a small amount of energy to remove outermost e

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13
Q

1st ionisation energy increases

A

across a period

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14
Q

1st ionisation energy decreases

A

down a group

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15
Q

Once 1 e has been removed

A

more energy is needed to remove the second e

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16
Q

Ionic Radius (def)

A

the radius of an ion

17
Q

Cations are (postive ions)

A

smaller in radii and smaller than their parent atom (if all the v electrons are removed there is one less occupied energy level with no change in nuclear charge)

18
Q

Anions are (negative ions)

A

larger in radii and are bigger than their parent atom (if there are more electrons in the valence level so there is greater e- to e- repulsion with no change in nuclear charge)

19
Q

Shape Template

A

number of e clouds around central atom
e are negatively charged and repel each other to maximize separation and minimize repulsion
parent arrangement and angle
Number of non bonding and bonding pairs
non bonding pairs contribute to shape but are not part of it
final shape

20
Q

Which atom is more electronegative

A

FONCl BrISCHP

21
Q

Solubility Def

A

The ability of a substance solute to dissolve (break up) in a given solute

22
Q

Exceptions in Electron Configuration are

23
Q

Ionisation Energy Factors-

A

The stronger the attraction of the nucleus to the electron, the more energy required to remove the electron.

24
Q

Electronegativity increase across a period due to

A

(atomic number) increasing positive charge due to increasing number of protons in the nucleus

Valence electrons across a period are in the same energy level which means

a decrease in atomic radius as valence electrons are pilled in closer due to strong electrostatic attraction

increase in first ionization energy- valence electrons are harder to remove

25
Electronegativity decreases down a group due to
increasing distance of the valence electron shell from nucleus so electrostatic attraction is reduced increasing number of electron shells shields the nucleus increase in atomic size- less attractive forces pulling the valence e to the nucleus decreasing first ionization energy- less attraction between nucleus and valence e- easier to remove
26
Shape Structure
1.Number of electron clouds 2.electron clouds repel around central atom “and maximise separation to minimise repulsion” 3.Parent shape 4. Angles 5.Number bonding and non bonding pairs 6.Non bonding pairs “contribute to shape but are not part of it”. 7.Shape
27
Electron Repulsion wording
These electron clouds are negatively charged and mutually repel around the central atom to maximize separation and minimize repulsion
28
Lone pairs in shape
contribute to the shape but are not part of it
29
Intermolecular Bonds (def)
The forces between the molecules that are broken when a substance melts or evaporates
30
Name the three types of intermolecular Bonds
Temporary Dipoles, Permanent Dipoles, Hydrogen Bonding
31
Temp Dipoles occur in
all molecules
32
Permanent Dipoles occur in
Polar Molecules
33
Hydrodgen Bonds occur in
polar molecules with H bonded to O, F or N
34
Solubility =
the ability of a substance(solute) to dissolve (break up) in a given solvent
35
A solute will dissolve if:
solute-solvent forces ≥ solvent-solvent and solute-solute force
36
Entropy Question Template
Entropy - degree of disorder or randomness Reactions will be spontaneous if total entropy change (system + surroundings) is positive. Entropy of system (ΔSsystem)– increasing or decreasing? Enthalpy of system (ΔH) - increasing or decreasing? Entropy of surroundings (ΔSsurroundings)– increasing or decreasing? Total entropy change – positive or negative?
37
Polarity of a molecule template
The molecule is [shape] and is [symmetrical/asymmetrical]. In the __-___ bond ___ is more electronegative than ____. The electrons will spend more time at __ than___ so __ is slightly negative and ___ is slightly positive. Therefore the __-___ bond is [polar/nonpolar] As the molecule is is [symmetrical/assymetrical] the [dipoles cancel/ don’t cancel] and so the molecule is [polar/non polar].