Week 9 - Nutrients Flashcards

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1
Q

How do plant roots absorb nutrients?

A
  1. Most nutrients absorption is passive and are taken up dissolved in water and is transported via the apoplast and symplast.
  2. Nutrients must be in the soil water, and that the water potential of the plant must be lower than that in the soil for water (and thus the dissolved nutrients) to move into the plant.
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2
Q

Describe the properties of essential nutrients?

A
  1. Plant must be unable to complete its life cycle in the absence of that particular element.
  2. Action of the element must be specific, and not able to be corrected or prevented by supplying any other element.
  3. Effect of the element on the plant must be direct. This precludes indirect effects such as alteration of soil pH, effects on concentration of other ions at the root surface, and effects on both pathogenic and non-pathogenic organisms which might limit plant growth.
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3
Q

Define the term macronutrient?

What are the macronutrients essential for plant growth?

A

Essential elements required in large amounts (>5-10 kg of element ha-1) or occur in high concentrations in normal plant tops (>0.1% of the dry matter).

These include:

C, H, O, N, P, K, S, Ca, Mg

C is obtained from CO2 in the air,
O from O2 in the air
H from water, originally from the atmosphere.

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4
Q

Define the term micronutrient?

A

Essential elements required in low concentration for normal plant growth are referred to as micronutrients (less than 1 kg of element per ha).

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5
Q

What are the forms of essential elements absorbed by plants?

A

Element Chemical formula of the form taken up by plants
Nitrogen NH4+, NO3-
Phosphorus H2PO4-, H2PO42-
Sulphur SO42-
Calcium Ca2+
Magnesium Mg2+
Potassium K+

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6
Q

What is required before plant uptake of nutrients can occur?

A

Before plant uptake can occur, the nutrient must be;

  • soluble; or
  • be in or capable of being turned into the plant available ionic form.
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7
Q

Why does elemental Sulphur not produce rapid growth response in plants?

A

Elemental sulphur (S) is neither soluble nor in the plant available form.

S has to be oxidised to SO42- by microorganisms before it is available so its application will not produce rapid growth response in plants.

In fact, the responses are gradual over periods of the order of months.

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8
Q

What happens to plant growth as nutrient supply is increased?

A

Zone A: The yield increases with nutrient supply, i.e. there is a nutrient deficiency. Note that this is not a straight line increase but is curved. At low nutrient supply, the increase in growth to extra nutrient is large but at higher levels of nutrient supply, extra nutrient produces less growth.

Zone B: Additional nutrient does not increase growth, i.e. the nutrient does not limit yield. The yield is limited by another nutrient, environmental or genetic factors.

Zone C: Additional nutrient decreases yield, i.e. the nutrient supply is in excess and toxicity is occurring.

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9
Q

Why can Molybdenum deficiency occur in acidic soils?

A
  • There are two types of nutrient deficiency, absolute and induced. Both can occur with molyledenum.
  • Some soils simply do not contain sufficient Mo to supply plants, it’s just not in the soil - an absolute deficiency.
  • Molyledenum availability is high at neutral soil pH (pH 6-7). However it is highly insoluble at low pH (pH <5) so acidity can induce a Mo deficiency
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10
Q

Why does “blossom end” rot a Ca deficiency occur in tomatoes?

A

“Blossom end” rot is an example of cation antagonism (a nutrient interaction).

High concentrations of any one cation can reduce the uptake of another nutrient present in a cationic form.

Application of high rates of fertiliser can reduce uptake of Ca by tomatoes and result in “blossom end” rot.

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11
Q

Explain why adding one nutrient may not result in a positive yield response?

A
  • When there are multiple deficiencies, for example, both N and P, if only N is added no response may be obtained because the P deficiency remains.
  • The yield response from addition of both N and P is much greater than the response to both applied separately. This is an example of a nutrient interaction.
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12
Q

Why can non-essential elements cause problems in plants?

A

Occasionally, they cause problems when present in large concentrations in soluble forms.

Under these conditions, they result in toxicities as they interfere with normal plant metabolism, e.g. Al, Pb, and Cd.

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13
Q

In addition to other mechanisms, how can nutrients resist leaching via immobilisation?

A

Nutrients can resist leaching by being immobilised into the organic fraction, that is, incorporated into microbial tissue of microorganisms.

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14
Q

How do cation/anion exchange sites impact nutrient retention?

A

Clay minerals and organic matter, develop electro-static charge on the surface of clay sized particles.

On both of these materials, the charge is normally negative so only the cations (the positively charged ions) such as K+, Mg2+, Ca2+, NH4+ are attracted to the surface.

The link between the solid particle and cation is simply one of electrostatic attraction.

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15
Q

Describe the two types of charge developed on soil solids.

A

Permanent charge - the concentration of charge on the soil particles does not change with the conditions in the soil solution. This type of charge results from isomorphous substitution in the clay layer silicate minerals.

Variable charge - the concentration of charge on the soil particles changes with the conditions in the soil solution.

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16
Q

On organic matter, describe why the concentration of charge on the soil particles changes with the conditions in the soil solution.

A

On organic matter most of the charge is derived from the dissociation of carboxyl groups:

R - COOH ⟺ R - COO- + H+

This equilibrium equation shows that the negative charge on the organic matter will increase if the H+ concentration decreases, that is the pH is high.

Conversely the charge on the organic matter will decrease as the H+ concentration increases, that is the pH is low.

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17
Q

Define cation exchange capacity (CEC)

A

The total concentration of negatively charged sites in a mass of soil is called the ‘cation exchange capacity’, C.E.C.

The higher the C.E.C. the greater the quantity of cations that can be retained from the soil solution.

18
Q

What are the units used for CEC?

A

Measured in centimoles of charge per kilogram of soil (abbreviated to cmoles + kg-1).

19
Q

Other than the cations themselves, what soil constituents influence the CEC of a soil.

A
20
Q

List 3 soil conditions necessary for SO42-, NO3-o, and CL- to be retained by electrostatic attraction to the surfaces of inorganic soil colloids.

A

When:

  • organic matter concentrations are low, and
  • the soil pH is acid (<5), and
    iron and/or aluminium oxides are present
  • the Fe and Al oxides can develop a positive charge.

In these soils, the anions Cl-, SO42- and NO3-, can be attracted to clays. Since this is reasonably unusual, SO42- and NO3- are normally rapidly lost by leaching.

21
Q

Explain why copper is often deficient in peat soils

A

Various chemical groups on organic matter are capable of bonding ions, especially Fe, Mn, Zn and Cu, to the organic matter surface, e.g.

For example highly organic or peaty soils commonly have Cu deficiencies as the Cu is made unavailable.

A chelate is formed when a cation is held between adjacent functional groups on organic matter. If the organic molecule is small, the cation remains in solution. But if it is a large humus molecule, the cation is not in solution and plant unavailable.

22
Q

Define exchangeable cations and soluble cations.

A

The cations attracted to the cation exchange sites are called exchangeable cations while those remaining in the soil solution are called soluble cations.

When fertiliser, for example, KCl is applied, large quantities of the cation, potassium are added to a soil. Under those conditions, part of the added K+ can be attracted onto the solids by displacing cations already present on the solid.

The added K+ displaced the exchangeable Ca2+ into solution. The K+ was attracted to the surface to become exchangeable K+.

This process of changing one cation for another is called ‘cation exchange’.

23
Q

What is the normal composition of cations on exchange sites in soils with a neutral pH?

Why does this composition occur?

A

In soils with a neutral pH, the normal composition of cations on the exchange sites is Ca2+ 75%, Mg2∓ 20%, K+ 5% (in some soils Na+ may be a major constituent, i.e. exchangeable Na+).

This composition of cations on the CEC sites occurs as not all cations are attracted with the same strength, i.e. Al3+ > Ca2+ > Mg2+ > K+ > Na+

24
Q

What is the normal composition of cations on exchange sites in acidic soils?

A

Al3+ and some H+ can be present in proportions up to 50% of the exchange sites.

25
Q

Define chemical adsorption

A

Some ions, especially phosphate and molybdate, can be attracted to the solid surfaces and are bound by a chemical (covalent) bond rather than being retained by electrostatic attraction.

Since these covalent bonds are strong, the P and Mo are released only slowly into the soil solution. There is some debate about the long term availability of these products.

26
Q

Describe what happens when high levels of some ions are released into soil.

Describe what happens with monocalcium phosphate dissolves in soil.

A

Various precipitation reactions occur when high levels of some ions are released into soil.

When monocalcium phosphate from superphosphate dissolves in soil the phosphate is hydrolysed releasing phosphoric acid.

The acid can dissolve soil minerals releasing Fe and Al ions into solution or in Ca rich soils, Ca.

The high concentration of phosphate, iron and aluminium results in the precipitation of iron and aluminium phosphates of low solubility. In calcareous soils calcium phosphate precipitates are formed.

27
Q

Explain why K+ fertiliser which is fixed is only gradually taken up by plants.

A
  • Cations can move between the layers of the layer silicate minerals . If the cations are the same size as the holes in the layer crystal plates, namely K+ and NH4+, the layers then collapse together, trapping the ions between the layers. The process of trapping of K+ or NH4+ by this mechanism is called potassium or ammonium fixation.
  • The fixed K is slowly released back into the soil solution.
  • Other cations such as Ca2+ and Mg2+ are not involved in this fixation process as they do have the ion size to fit into the cavities in the layer silicate plates.
28
Q

Describe how complex formation by organic matter can influence retention of nutrients by soils.

A

Complex formation by organic matter

Various chemical groups on organic matter are capable of bonding ions, especially Fe, Mn, Zn and Cu, to the organic matter surface.

The bonds are strong and are specific for the cation micronutrients.

29
Q

Why are non-essential nutrients also found with essential nutrients in plant tissue?

A

These elements were dissolved in the soil water and are taken up by the plants as they absorb the water (remember passive nutrient uptake)

30
Q

What are the three criteria necessary to be satisfied before a nutrient can be considered to be essential?

A
  1. The plant must be unable to complete its life cycle in the absence of that particular element.
  2. The action of the element must be specific.
  3. The effect of the element on the plant must be direct.
31
Q

Name the three types of soil materials which give rise to the cation exchange capacity in soils. What is the soil pH’s range for which of these sites are actually capable of attracting cations?

A
32
Q

How does soil pH affect the charge on sesquioxides and what does this effect.

A

When organic matter concentrations are low, and the soil pH is acid (<5), and iron and/or aluminium oxides are present the Fe and Al oxides can develop a positive charge.

This increases positively charged sites called ‘anion exchange sites’ and therefore anions Cl-, SO42- and NO3-, can be attracted to clays.

Since this is reasonably unusual, SO42- and NO3- are normally rapidly lost by leaching.

33
Q

Name the mechanisms in soil responsible for the retention of nutrients in soil.

A

a. Cation/anion exchange sites
b. Chemical or specific adsorption
c. Formation of insoluble compounds
d. Cation fixation by clays
e. Complex formation by organic matter

34
Q

Rank how rapidly each of the following are lost from the soil by leaching and explain your reasoning?
a) K +
b) H2PO4-
c) NO3-
d) Ca2+

  • Rank 1 through to 4 for fastest to slowest, respectively
A
35
Q

Define cation antagonism.

Give one example of cation antagonism.

A

High concentrations of any one cation can reduce the uptake of another nutrient present in a cationic form.

For example, application of high rates of fertiliser can reduce uptake of Ca by tomatoes and result in a condition called “blossom end” rot, a Ca deficiency.

36
Q

Describe two symptoms of nutrient deficiencies.

A
37
Q

List 3 soil conditions necessary for non-specific adsorption of nitrate to soil colloids.

A

i. organic matter concentrations are low, and
ii. the soil pH is acid (<5), and
iii. iron and/or aluminium oxides are present

Therefore, Fe and Al oxides can develop a positive charge and nitrate can be attracted to clay.

38
Q

Name 2 cations that are fixed by layer silicate clay minerals.

A

On layer silicate clays, the charge is normally negative so the cations (the positively charged ions) such as K+, Mg2+, Ca2+, NH4+ are attracted to the surface.

39
Q

Explain the various mechanisms by which phosphate is retained in the soil; use headings to highlight each mechanism.

A
40
Q

Define specific adsorption.

A

Some cations can be specifically adsorbed if in a hydroxy form, for example (ZnOH)+, (CuOH)+