Week 5 - Air Pollution Flashcards

1
Q

What is solar radiation at Earth’s distance for the Sun?

A

~1370 W m-2 (solar constant ,So)

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2
Q

% of Solar,short wave radiation (SW) absorbed by the Earth?

A

~70%

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3
Q

% of Solar,short wave radiation (SW) reflected by the Earth

A

~30%

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4
Q

Global mean mole fraction of CH4?

A

~1800 ppbv

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5
Q

Atmospheric lifetime of methane?

A

~10 years

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6
Q

How does atmospheric mixing time compare to a species’ lifetime in determining its distribution?

A

If 𝜏𝑥 ≪ 𝜏mixing , the species is removed much faster than it can be mixed throughout the atmosphere, the species is removed much faster than it can be mixed throughout the atmosphere.
Therefore, mixing has little influence on its spatial distribution, and the species remains concentrated near its source.

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7
Q

What are the main sources of methane (CH₄)?

A

Natural: Wetlands, termites, ocean sediments
Human-made: Agriculture (livestock, rice), landfills, fossil fuels, biomass burning

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8
Q

What are some examples of non-CO2 greenhouse gases and their characteristics?

A

Long-lived: N₂O (Nitrous Oxide), CFCs (Chlorofluorocarbons), CH₄ (Methane)

Short-lived: O₃ (Ozone)

Interact with outgoing long-wave (LW) terrestrial radiation

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9
Q

How do aerosols (PM) impact climate?

A

Aerosols scatter and absorb incoming short (SW) solar radiation
E.g. sulphate, nitrate, organic aerosols , black carbon

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10
Q

What factors influence radiative forcing, which impacts climate?

A

Change in atmospheric concentration from pre-industrial to present-day.

Efficiency in impacting radiation (e.g., spectroscopy, aerosol size/composition).

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11
Q

How are future impacts of emissions of different species compared?

A

Using Global Warming Potentials (GWP) based on:
(Radiative Forcing of GHG × Atmospheric Lifetime) / (Radiative Forcing of CO₂ × Atmospheric Lifetime of CO₂)

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12
Q

What is the basic concept of the simple climate model involving blackbody radiation?

A

Incoming energy: Solar (short-wave) radiation of ~1370 W m².
Earth’s albedo: Earth reflects ~30% and absorbs ~70% of incoming solar radiation.
Outgoing energy: Earth emits long-wave radiation back into space (Stefan-Boltzmann Law).

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13
Q

Why does the effective temperature of Earth differ from its average surface temperature?

A
  • Effective temperature: ~255 K (-18°C), ~33 K colder than Earth’s surface temperature.
  • This is due to greenhouse gases in the atmosphere, which absorb and emit long-wave radiation, keeping Earth’s surface warmer.
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14
Q

Effective temperature vs surface temp of Earth?

A

Effective temp (Te)= 255k (-18C)
Surface temp (T0) = 288K (15C)

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15
Q

Where does the effective temperature originate?

A

~5.5 km altitude where temps are at 255K

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16
Q

What can we use to look at past changes in CO2, CH4, N2O, Halocarbons?

A

Data from ice cores

17
Q

Why can’t we look at data from ice cores for most pollutants?

A

But most air pollutants are too reactive/short-lived: ozone & aerosols are not well sampled/preserved by ice cores
- to estimate pre-industrial levels, need to construct models that can simulate the past atmospheric composition

18
Q

What is radiative forcing

A

The net change in Earth’s energy balance caused by a climate driver e.g. GHGs, aerosols

19
Q

What gases are long-lived greenhouse gases?

A

CO2,CH4,N2O,CFCs

20
Q

What are aerosols and how do they affect climate?

A

Tiny particles that scatter/absorb shortwave solar radiation,causing cooling (e.g. sulphates) or warming (e.g. black carbon)

21
Q

What is blackbody radiation?

A

Radiation emitted by an ideal object that absorbs all incoming radiation. The Sun and Earth approximate blackbodies

22
Q

What does Wien’s Displacement Law describe?

A

It gives the wavelength at which a blackbody emits most energy:

𝜆=2897/𝑇 (μm)

23
Q

What is the Earth’s incoming solar energy (solar constant )

A

~1370 W/m2 averaged to ~342W/m2 across the Earth’s surface

24
Q

How much solar energy does Earth reflect and absorb?

A

Reflects ~30% (albedo = 0.3), absorbs ~70%.

25
What are shortwave and lingwave radiation?
Shortwave (SW)- Incoming solar radiation Longwave (LW): Outgoing terrestrial (Earth-emitted) radiation
26
Example of climate feedback mechnaisms?
-Positive: Water vapor, ice-albedo - Uncertain: clouds, ocean feedbacks
27
What does radiative forcing depend on?
- change in atmospheric concentration (PD-PI) - efficiency in impacting radiation (spectroscopy; aerosol size/composition)
28
How do aerosols and ozone differ in their spatial impact?
Aerosols: Short-lived, boundary layer Tropospheric O₃: Lifetime ~1 month, concentrated in upper troposphere Well-mixed GHGs: Long-lived, globally distributed
29
What is a trade-off in emissions control policy?
Reducing SO₂ improves air quality but removes cooling effect (negative RF), potentially accelerating warming.
30
Why does sulfur dioxide (SO₂) lead to cooling in the atmosphere?
SO₂ forms sulfate aerosols, which: - Reflect sunlight (shortwave radiation) back into space - Increase cloud reflectivity by acting as cloud condensation nuclei This reduces solar energy reaching Earth’s surface, causing temporary, localized cooling (negative radiative forcing).
31
What is the effective temperature of Earth, and why is it lower than the surface temperature?
Tₑ ≈ 255 K; lower because it’s the radiation-emitting temperature at ~5.5 km altitude due to the greenhouse effect.
32
What is GWP and why is it used?
Global Warming Potential compares the warming effect of a gas to CO₂ over a set time frame (e.g., 100 years).
33
How does CH₄ compare to CO₂ in GWP?
CH₄ is ~25× more potent than CO₂ over 100 years; ~72× over 20 years.
34
Why can’t we measure historical ozone and aerosols from ice cores?
They are too reactive/short-lived to be trapped and preserved in ice.
35
What is the main purpose of climate policy agreements like Kyoto and Paris?
To limit GHG emissions and prevent dangerous levels of global warming (well below +2°C).
36
What is the Stefan-Boltzmann Law and its significance in climate science?
F=σT ^4 ; relates temperature of an object to the energy it radiates—used to model Earth’s energy balance.
37
What do we use models of atmospheric composition
To simulate future ozone and aerosol models using prior/current observations
38
Calculation for Mass mixing ratio?
Volume Mixing Ratio * (Mx/Md)