Week 5 Flashcards

1
Q

Angular momentum equation

A

L = r x P

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2
Q

Magnitude of angular momentum

A

From crossproduct, rpsin theta

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3
Q

What are central forces?

A

Force acting only in radial direction

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4
Q

How do central potentials arise

A

From central forces (Acting radially only)

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5
Q

What are some central potentials?

A

Gravity, coulomb

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6
Q

What happens to L in a central potential?

A

L (angular momentum) is conserved

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8
Q

Prove L conservation in central:

A

L = r x p + r x p
= (mr x r) + (r x F ) f=central force
= 0 + 0

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9
Q

Which operators commute?

A

Position, momentum, L^2

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10
Q

What is formula for rotational energy of single particle?

A

E rot = L^2 / (2m r^2)

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10
Q

What is significant about commutation?

A

If observables commute, can measure both simulateously and have shared eigenfunction

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11
Q

Which observables don’t commute?

A

Not position and momentum

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12
Q

What is the range of the polar angle?

A

0 to Pi ( polar bears seat pie)

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13
Q

What is the angle of the azimuthal angle?

A

O to Pi (A to Z = whole)

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14
Q

What is the linear momentum operator?

A

P hat sub i = - is bar d/dri

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15
Q

What is the linear momentum operator for i?

A

L hat sub i = - i hbar (r subj * (d/d rsubk) - (r sub k * (d/d rsubj))

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16
Q

Why use L^2?

A

Because L does not commmute

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17
Q

What is the operator L ^2 related to?

A

Rotational energy

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18
Q

What commutes with L?

A

L^2

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19
Q

What are the features of the eigenfunctions for L and L squared?

A

No dependence on r

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20
Q

What can you say about Eigen values for common eigenfunctions?

A

Nothing. They do not have to be the same.

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21
Q

What are the boundary conditions for the eigen functions?

A

As they are based on theta and phi, they are bounded and cannot go to plus or minus infinity

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22
Q

What is the eigenvalue associated with the angular momentum operator?

A

Mh

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23
Q

What does the eigenvalue for angular momentum tell us?

A

Angular momentum is quantised

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24
Q

What is the difference between quantum and classical angular momentum?

A

Quantum is quantised even in free. Space

25
What are the requirements to have solutions to the legendre polynomial?
1. Lambda equals L (L plus 1)H bar^2 2. L is greater or equal to the magnitude of M. 3. L can only be zero, one, two… And only positive.
26
How many way functions in the solutions to Legendre polynomials?
For each combination of L & M. There is a specific wave function.
27
How many possible values of M for each L?
2L +1
28
What is the operator for the magnitude of angular momentum?
L hat = SQRT (L^2)
29
What does the operator L sub Z represent?
The projection of L onto the Z axis
30
What is the value of Lz?
Mh
31
What is the value of Lz and why?
It is always less than the value of L because the Angular momentum can never point exactly a along one axis
32
How can you define LX and LY once you have defined Lz?
They remain undefined
33
On a diagram with L on each axis, what does the circles represent?
The definite values of Lz lead to totally uncertain values of Alex and LY, which are the circles
34
On a diagram with L on each axis, what does the radius of the circle represent?
This is the magnitude of L and equals l(l+1) hbar
35
On a diagram with L on each axis, what does the height of the circles represent?
L
36
What type of polynomials are spherical harmonics?
Homogenous polynomials in XYZ of degree L
37
What requirements are circle harmonics uniquely specified by?
1. Y sub L Sup +/- M is proportional to a polynomial in z^ and X^2 + y^2 all * (x + iy) ^ magnitude of m 2. Must be orthogonal to al previous spherical harmonics
38
What do blue peanuts represent?
Real numbers
39
What do yellow peanuts represent?
Imaginary numbers
40
What can you derive by considering the Hamiltonian operator in 3-D in polar coordinates?
The Hamilton operator in 3D equals Hamilton operator radially plus L^2 operator (theta,phi) divided by(2MR rsquared)
41
Explain you derive by considering the Hamiltonian operator in 3-D in polar coordinates?
The Hamilton operator in 3D equals the radio kinetic and potential energy, plus the angular kinetic energy
42
Which operators have common eigenfunctions?
Hamiltonian, Lz L^2
43
What is the energy eigenfunction equation?
U (r, theta, phi) = R (r) Y (sub L sup m) (theta, phi)
44
What is the radial equation?
45
What is different in the radial equation compared to the standard energy eigenvalue equation?
L(L+1) term looks like an additional potential
46
What is the centrifugal force?
The additional term in the radial equation for potential, which makes up part of the repulsive term, so objects slow as r tends to 0, and then speed up as they are repulsed
47
48
What is the Eigen value for Lz?
Mh, m = 0, +/-1, +/- 2 …
49
What is the Eigen value for L^2?
L (L+1) hbar^2 L = 0,1,2…
50
What is the name for the eigenfunctions of Lz and L^2?
Spherical harmonics
51
What do spherical harmonics depend on?
No radial dependence
52
What does the radial equation determine?
In 3-D, the radial wavefunctions
53
Which quantum number labels energy
N = principal, quantum number
54
Which quantum number labels angular momentum?
L = orbital, quantum number
55
Which quantum number labels the direction of angular momentum?
M = magnetic quantum number
56
What does the z-component of angular momentum signify?
“Direction”. Of angular momentum
57
What can lift energy degeneracy?
Magnetic field
58
How do you determine the degeneracy of energy?
As each energy has(2L + 1) associated with functions, it is (2L + 1)-fold degenerate