Week 3 Gases Flashcards
Kinetic Molecular Theory
Gases are made up of particles in constant random motion
Collisions result in a change in direction of motion
3 Assumptions of the particulate model
1
- Gases are negligibly small (particle size)
- Average kinetic energy is proportional to temperature in K KEavg=3/2RT (Average kinetic energy DOES NOT depend on chemical identity)
- Elastic collisions with each other and vessel (no loss of KE)
Pressure equation
P=F/A (force/area)
P=dgh (densityxgravitational constantx height of fluid)
What happens to a bag of potato chips at the top of a mountain
Bag expands because there is fewer atmospheric air particles colliding with the chip bag
Manometer
What does each part of the equation mean (what are the constant numbers)
𝝙P (in Pa)=dgh
𝝙P= positive differential in pressure on both sides
density of manomter fluid dhg=12.384 g/ml
g=gravitational constant (9.8 m/s2)
h=difference in height of fluid in mm
Explains what happens to pressure if the height of gas is lower higher?
- hgas< hatm
Pgas>Patm
Pgas (in PA)=Patm+dgh
Pgas (in mmhg)=Patm+h - hgas>hatm
Pgas<Patm
Pgas (in PA)=Patm-dgh
Pgas (in mmhg)=Patm-h
What are the ways to describe gases (physcial properties)
Pressure- how forceful are collisions with the vessel
Volume- how much space does the gas take up
Temperature- how fast are the particles on AVG
Moles- how many particles
Avogadro’s
What are constants, what is the equation, is graph linear
T,P
V1/n1=V2/n2
YES
Boyles
What is constant, what is the equation
n,T
P1V1=P2V2
Graph is NOT linear
Charles
What is constant, what is the equation, is the graph linear
n,P constant
V1/T1=V2/T2
What makes gases ideal
No attractive forces
Molecules have complete freedom to spread out and take up all the space in the vessel
Particles are negligibly small (particles volume not accounted for)
Molar Volume and equation deriviation
Vm=RT/P
Volume that 1 mol of gas takes up
What are STP conditions, what does 1 mol of gas occupy?
T
Temp: 273 K
P: 1 atm
Amount: 1 mol
1 mol=22.4 Liters
Density Ideal gas law deriviation
d=PM/RT
M is molar mass