week 2 thermo Flashcards

1
Q

what is heat capacity ?

A

heat energy required to raise the temperature of an object by 1 degree or 1K

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2
Q

what is the second law off thermodynamics (clausius and kelvin)

A

clausius - no process is possible who’s sole result is the transfer of heat from a body of cold temp to a body of higher temp meaning heat can not go from hot to cold

kelvin - no process is possible in which the sole result is the absorption of heat from a reservoir and its complete conversion of work meaning all the heat will and can not be turned into work some will sink cold

entropy reversible heat reaction.

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3
Q

why does the entropy of an isolated system always increase?

A

because there is many ways to maintain the structure of a high entropy structure compared to a few ways of doing this for a low entropy system therefore it is mathematically overwhelmingly more likely that low entropy highly ordered structures will transfer into high entropy disordered structures

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4
Q

what makes a chemical reaction feasible (spontaneous)

A

the entropy of the universe must increase

the Gibbs energy of the system must decrease

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