Week 1 Revision of Thermodynamics Flashcards
1
Q
what is the 0th Law of Thermodynamics
A
concept of thermal eqm leads to concept of Temp
in thermo eqm if at same temp
2
Q
what is the 1st Law of Thermodynamics
A
dE = dQ + dW
3
Q
what is the Kelvin Planck statement
A
Impossible to build an engine which in a cycle will produce no effect other than the extraction of heat and performance of work
4
Q
what is the Clausius statement
A
Impossible to build a fridge which in a cycle will produce no effect other than the transfer of heat
5
Q
what is entropy eqn
A
dS = dQ/T
6
Q
what is always true of entropy
A
it never decreases and only remains 0 for reversible adiabatic processes
7
Q
what is the FTR eqn
A
dE = TdS - PdV
8
Q
what are the two Helmholtz Free energy eqns
A
F = E - TS dF = -SdT -PdV
9
Q
what are the two Gibbs Free energy eqns
A
G = E -TS + PV dG = -SdT + VdP
