Water Treatment Flashcards

1
Q

What are the 4 basic operations for water treatment

A

Coagulation/flocculation
Sedimentation
Filtration
Disinfection

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

What does aeration do?

A

Increases oxygen content and reduces carbon dioxide content

Can cause colour change if oxides present

Reduces concentration of taste and odour causing substances

Removes volatile synthetic organic chemicals (SOCs) considered hazardous to public health

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

How does aeration work?

A

Scrubbing action caused by turbulence from water and air mixing together. Fe and Mn fall out of solution

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Methods of aeration

A

Mechanical aerators: employ motor-driven impellers alone or in combination with air injection devices. They are also installed at water reservoirs to control taste and odor.

Pressure aerators: Typically used for oxidising iron and manganese. There are two basic types of pressure aerators in which either compressed air is injected directly in pressurised pipeline or water is sprayed into the top of a closed tank while the tank is continuously supplied with compressed air.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

What is coagulation?

A

Coagulation refers to a reduction in the forces which tend to keep suspended particles apart.

Coagulation is the process of inducing contacts between a chemical (coagulant) and colloidal particle to cause a reaction – The reaction product is called a microfloc.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

What is flocculation?

A

Flocculation refers to the joining together of small particles into large settleable and filterable particles.

Inducing the growth of microflocs to form flocs.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

What are colloidal particles?

A

Suspended minerals, clay, silt, organic debris and microscopic organisms ranging in size from about 0.001 to 1.0 microns

Settling rate of colloidal particles is quite low – removal by sedimentation is not practicable, unlike larger ones like sand/silt.

Chemical coagulation and flocculation required to aggregate the smaller particles to form larger particles to settle out in sedimentation.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

What are the most commonly used coagulants?

A

Aluminum sulphate (filter alum) and Iron salts

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

Why does allum have a pH range of 5-8 as a coagulant?

A

At pH of 5-8 allum is least soluble. This is desirable as we want the particles to precipitate out and form flocs.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

What is sedimentation?

A

the gravitational settling of suspended particles that are heavier than the surrounding fluid.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

What is the sludge layer?

A

Suspended particles retained at the tank floor

Heavier particles with ρparticles > ρfluid settle under gravitational forces

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

What is the scum layer?

A

Suspended particles retained at the water surface

Flotation: Lighter particles with ρparticles < ρfluid tend to move vertically upward

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

What is Plain sedimentation?

A

The use of a pre-sedimentation basin for grit (small loose stone or sand particles) removal.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

For wastewater treatment, why is sedimentation used?

A

Grit (or sand and silt) removal.
Suspended solids removal in primary clarifier.
Biological sludge removal in activated sludge.
Humus removal in trickling filter final clarifiers.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

What is filtration?

A

A process used for separating suspended or colloidal impurities from a liquid by passing the liquid through a porous medium.

Polishing step to remove small flocs or precipitant particles not removed after sedimentation of coagulated or softened water.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

Should filtration be relied upon for health protection?

A

No

Under certain conditions, filtration may serve as the primary turbidity removal process – e.g. direct filtration of raw water.

Although filtration removes many pathogenic microorganisms (e.g. Giardia & Cryptosporidium), it should not be relied upon for complete health protection.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
17
Q

Describe how filtration is commonly carried out

A

The most commonly used system involves passing water through a stationary bed of granular medium (filter).

Solids in the water are retained by the filter medium. Several modes in granular filtration medium (Upflow, biflow, pressure & vacuum).

The most common in practice is gravity filtration in a downward mode – the weight of the water above the filter column provides the driving force.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
18
Q

Key parameters that affect filtration

A

Grain size ditribution
Porosity
Grain density
Effective size parameter

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
19
Q

What is slow sand filtration?

A

These microorganisms assist the filtration process by removing contaminants, though water temperatures below 10°C may slow them. Sand that hosts these organisms is said to be “ripened” and is preferable to clean or new sand. Depending on water content and temperature, it may take several weeks or months to ripen sand. The process eventually clogs the sand bed and slows flow rates to the point that it must be unclogged, typically by reversing the flow, or “backwashing”

Most suspended particles and organic materials are decomposed on theschmutzdeckelayer. Particles in raw water go through the sand media filter. The restrained particles become food for the bacteria on theschmutzdeckelayer.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
20
Q

What is disinfection?

A

The process of destroying or inactivating disease-causing pathogenic organisms that may be harmful to human health in water.

Chemical means – Chlorine, Ozone, etc.
Non-chemical means – Heat, UV irradiation.

21
Q

What is sterilisation?

A

The removal and destruction of all living microorganisms, including pathogenic and saprophytic bacteria, vegetative forms and spores.

22
Q

What are the 3 basic strategies to keep microbiological contaminants out of drinking water?

A

Keeping microbiota out of water source
Treating water to remove contaminants
Maintaining safe water distribution system

23
Q

What are the 2 components of disinfection?

A

Primary disinfection – inactivation of microorganisms in the water.

Secondary disinfection – maintaining disinfecting residual in the distribution system.

24
Q

How can pathogen inactivation be carried out?

A

Destruction of cellular structure (damage of nucleic acids & proteins).

Interference with metabolic activities and protein synthesis.

25
Q

What are indicator organisms?

A

Used to assess the presence or absence of pathogens such as E.coli

26
Q

What is chlorine demand?

A

The demand by inorganic and organic materials

It is the difference between the amount of chlorine applied to the water and the amount of residual chlorine after a given contact time.

27
Q

Chlorine dose equation

A

Chlorine Dose = Chlorine Demand + Chlorine Residual

Where:
Chlorine Residual = Combined Chlorine Forms + Free Chlorine

28
Q

What factors affect water treatment process selection?

A

Cost effective
Meet Water Quality regulations - standards at all times
Robust, to meet predicted changes in raw water quality Meet demand forecasts and short term variations
Must not have adverse effects on distribution system

Physical
Chemical
Biological
- storage, screening, settlement, filtration (by sand) - coagulation/flocculation, disinfection
- filtration (using Granular Actived Carbon)

29
Q

What are the sources of wastewater?

A

Domestic / sanitary wastewater or sewage
Industrial wastewater
Stormwater
Infiltration/Inflow

30
Q

Examples of industrial wastewater

A

Iron and steel: Typical pollutants include metals, phenols, cyanide, acids, BOD and COD.
Mining: Acids, metals, salts and suspended solids (SS).
Textile & leather: Solids, chromium, sulfates, and BOD.
Microelectronics: Organic chemicals & COD.

31
Q

Three major components of a wastewater system

A

Collection/conveyance
Treatment
Disposal/reuse

32
Q

Types of wastewater collection systems

A

Sanitary Sewer
* Collects commercial and household wastes (sometimes industrial).
* A sanitary sewer does not include any storm water.

Storm Sewer
* Collects runoff from streets, land, and roofs.
* Historically, this has been discharged to the stream without treatment.

Combined Sewer
* Collects sanitary and storm water.
* During storms, high flows can create short-term overloading conditions at treatment plant, impacting treatment efficiencies.

33
Q

Characteristics of wastewater

A

Suspended solids: - may lead to the development of the sludge deposits and anaerobic conditions when untreated wastewater is discharge to environment.

Biodegradable organics: Composed principally of proteins, carbohydrates and fats. If wastewater is discharged untreated to the environment their biological degradation may lead to the depletion of natural oxygen resources and development of anaerobic conditions

Nutrients: Both nitrogen and phosphorus are essential nutrients for growth. When discharged to aquatic environment, these nutrients can lead to the growth of undesirable aquatic life (algae).

Heavy metals: are usually added to wastewater form commercial and industrial activities and may have to be
removed if the wastewater is to be reused.

Pathogens: Communicable diseases can be transmitted by the pathogenic organisms that may be present in wastewater

34
Q

Common wastewater parameters used in industry

A

Biochemical (Biological) oxygen demand (BOD)
Chemical oxygen demand (COD)
Total Organic Carbon

35
Q

What is BOD?

A

Biochemical (or biological) oxygen demand (BOD) is the most commonly used parameter to define the strength of a municipal or organic industrial wastewater.

BOD is a measure of the amount of oxygen needed (in mg/l)) by bacteria and other microorganisms to fully oxidise the organic matter present in a water sample.

It is of limited value when measuring the actual oxygen demand of surface waters, and extrapolation of test results to actual stream oxygen demand is questionable.

36
Q

What is COD?

A

The COD test measures the chemical oxidation of wastewater by using a strong oxidizing agent under acid conditions.

The COD test does not differentiate between biologically available and inert organic matter and measures the total quantity of oxygen required to oxidise all organic matter into CO2 and water.

COD values are always greater than BOD values, and the presence of toxic compounds in the sample do not affect COD measurements unlike the BOD test.

37
Q

BOD:COD ratio

A

One method of determining the biodegradability of contaminants is the use of a 5-day BOD test

Untreated Wastewater
≥ 0.5, easily biodegradable

It is known that for BOD5:COD ratio < about 0.3, the waste may have some toxic components or acclimated microoorganisms may be required for stabilization.

38
Q

What is TOC?

A

TOC is often used as a non-specific indicator of water quality. The test measures carbon, where the carbon is oxidized to CO2 by:

High-temperature catalytic oxidation.
Heated persulfate/wet chemical oxidation.
UV persulfate oxidation.

The test is unable to differentiate between biodegradable and non-biodegradable matter. Its main advantage is speed, determinations can be made within minutes, facilitating a greater number of measurements compared with either BOD or COD tests.

39
Q

Industrial Wastewater Pretreatment

A

It is required by regulatory agencies that industrial wastewaters are pre-treated prior to being released into the municipal sewer system. The rationale is to:

Get rid of materials that will not be treated by the municipal system. Specifically, to remove materials that inhibit the biological processes in secondary treatment.

For instance, silver ions are toxic to bacteria, and this would affect biological process in secondary treatment. Hence, silver ions are removed at pre-treatment before biological process so that bacterial performance is not affected.

40
Q

Preliminary wastewater treatment

A

Upon arrival via the sewer system, the wastewater is sent through a bar screen, which removes large solid objects such as sticks and rags.

Leaving the bar screen, the wastewater flow is slowed down entering the grit tank, to allow sand, gravel and other heavy material that was small enough not to be caught by the bar screen to settle to the bottom. All the collected debris from the grit tank and bar screen is disposed of at a sanitary landfill.

41
Q

Secondary wastewater treatment

A

Secondary treatment is a biological treatment process in which dissolved organic matter is removed from wastewater.

Sewage microorganisms are cultivated and added to the wastewater. The microbes use organic matter from sewage as food source leading to biodegradation of organic waste.

Accomplished by creating a rich environment for growth of a diverse microbial community.

42
Q

Secondary wastewater treatment process requirements

A

High microbial density.
Effective mixing – good contact between microbes and wastes.
Aeration – Provide high oxygen levels.
Design and operation – Provide favourable temperature, pH, nutrients (C, N, P).
Absence of toxic chemicals – control inputs from industrial sources.

43
Q

Tertiary wastewater treatment

A

Seeks to reduce the nutrient content of treated wastewater to prevent uncontrolled algae growth in surface water bodies.

Biological phosphorus removal.
Chemical precipitation of phosphorus.
Nitrogen removal (denitrification)

44
Q

Tertiary wastewater treatment processes

A

Micro/ultra membrane filtration
Reverse osmosis
Ozonation and ultraviolet disinfection.

45
Q

Reuse of wastewater

A

The wastewater can be recycled for direct and/or indirect potable reuse.

Indirect potable reuse: Replenish natural freshwater sources that supply drinking water, for e.g., to recharge underground aquifers or replenish surface reservoirs, diluted with naturally occurring freshwater.

Direct potable reuse: Recycled treated wastewater serves as a direct source of drinking water. It’s not discharged back into the environment.

46
Q

Resource recovery from wastewater - anaerobic digestion

A

Biogas can be used as a gaseous fuel to produce electricity and heat (co-generation) in a gas turbine or engine or in a boiler or furnace or cleaned and used as a natural gas substitute.

Digestate can be processed to produce liquor and fibrous material. The liquor can be used as fertiliser due to high levels of nutrients, while the fibrous material can be used as a soil conditioner as it has a low level of nutrients.

47
Q

Anaerobic digestion temperatures

A

AD systems operate in three main temperature ranges:

Thermophilic systems (50–60 °C)
Mesophilic systems (30–40 °C)
Psychrophilic systems (15–25 °C).

48
Q

Effect of operating conditions on anaerobic digestion

A

The value and stability of pH are very important during AD as the methanogenic bacteria are extremely sensitive to pH with the optimum range of 6.6 – 7.6.

Temperature is another important factor that can affect the growth rate and metabolism of microorganisms, hence the population dynamics in the anaerobic reactor. Increasing temperature leads to enhanced solubility of organic compounds as well as improved biological and chemical reaction rates and death rate of pathogens.

Alkalinity levels are best between 1,000 and 5,000 mg/L CaCO3.