Water Quality Concept Check L10 Flashcards

1
Q

The units of a rate constant depend on the order of the reaction. (True/False)

A

True

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2
Q

A negative reaction rate term (-R) means that the chemical is being consumed/generated in the reaction.

A

Consumed

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3
Q

A conservative substance undergoes reaction. (True/False)

A

False

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4
Q

Theta, called the ____________ describes the average time fluids spend in a reactor

A

Hydraulic resonance time

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5
Q

The PFR model may be applied to natural systems such as rivers as well as engineered systems.

A

True

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6
Q

A spike of contaminant moves through a CSTR/PFR as a plug, not mixing with the fluid in front of or behind of it.

A

PFR

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7
Q

Reaction kinetics describe the rate at which a reaction occurs (true/false)

A

True

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8
Q

As in a CSTR, the pollutant concentration in a pfr is always homogenous throughout the reactor. (True/false)

A

False

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9
Q

What is the overall order of the reaction described in the following rate law? R=k[C6H6][NO3-]2

A

Third order

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10
Q

Oxygen demand is

A

The amount of oxygen consumed by biota or reacted with chemicals

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11
Q

What is the max amount of oxygen in clean water and why?

A

9 mg/l because of Henry’s law

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12
Q

How does temperature affect DO?

A

Causes DO saturation level to decrease

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13
Q

How dues salinity affect DO?

A

Causes DO saturation level to decrease

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14
Q

How does elevation affect DO?

A

The partial pressure of oxygen decreases as elevation increases, so the DO saturation level decreases

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15
Q

How does turbulence affect DO?

A

A turbulent stream will replenish DO quickly while a slow, sluggish stream will replenish DO slowly

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16
Q

What processes affect the dissolved oxygen concentration in water?

A

1) oxygen transfer from atmosphere
2) aerobic biodegradation of organic
3) microbial nitrification
4) photosynthesis

17
Q

What depletes dissolved oxygen in water?

A

1) aerobic biodegradation of organics {organics converted to CO2}
2) microbial nitrification {ammonia converted to NO3-}

18
Q

What is theoretical oxygen demand (ThOD)?

A

Amount of O2 theoretically nessary to oxidize contaminant

19
Q

What is biochemical oxygen demand (BOD)?

A

Amount of O2 necessary if oxidation carried out by bacteria

20
Q

Is BOD or ThOD bigger?

A

BOD is always less than ThOD because some glucose is incorporated into new cells

21
Q

What is carbonaceous oxygen demand?

A

Oxygen required to oxidize C compounds

22
Q

What is nitrogenous oxygen demand?

A

Oxygen required to oxidize N compounds

23
Q

How do we measure oxygen demand for a water sample?

A

Procedure for BOD test:
1) take sample of water
2) add microorganisms
3) measure DO consumption by microorganisms over 5 days

Parameters: temperature 20°, conduct test in dark, need at least 2mg/L change in DO over 5 days