w1 Flashcards

1
Q

What is ‘k’? How is it found!

A

Rate constant. k= rate/concentration

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2
Q

What is the overall reaction order equation?

A

k = [A] ^m [B] ^n

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3
Q

What is overall reaction order?

A

– Zero-order reactions: the units of k are mol L-1 time-1
– First-order reactions: the units of k are time-1
– Second-order reactions: the units of k are L mol-1time-1

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4
Q

About orders:

A

Zeroth: Plot [A] vs T
First: Plot ln[A] vs T
Second: Plot 1/[A] Vs T

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5
Q

Properties of molecules that determine reaction rates?

A

Concentration of reactants
(increase concentration and reactions go faster)
* Temperature
(to make a reaction go faster, heat it. To slow it down you cool it).
* Steric effects
(You may not have thought of this, it is related to how molecules
run into each other, must have right orientation).
* Phase
(Reaction rate tends to go Gas>Liquid>Solid)

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6
Q

Collision Theory

A

Must collide, with sufficient kinetic energy, in the correct orientation

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