VESPr Flashcards
If the central atom has 2 electron pairs
sp hybridization, shape is linear
If the central atom has 3 electron pairs with 0 lone pairs
sp2 hybridization, shape is trigonal planar
If the central atom has 3 electron pairs with 1 lone pair
sp2 hybridization, shape is bent
if the central atom has 4 electron pairs with 0 lone pairs
sp3 hybridization, shape is tetrahedral. bond angles about 109.5 degrees
if the central atom has 4 electron pairs with 1 lone pairs
sp3 hybridization, shape is trigonal pyramidal
If the central atom has 4 electron pairs with 2 lone pairs
sp3 hybridization, shape is bent
if the central atom has 5 electron pairs with 0 lone pairs
the shape is trigonal bipyramidal
if the central atom has 5 electron pairs with 1 lone pair
the shape is seesaw
if the central atom has 5 electron pairs with 2 lone pairs
the shape is T-shaped
if the central atom has 5 electron pairs with 3 lone pairs
the shape is linear
if the central atom has 6 electron pairs with 0 lone pairs
the shape is octahedral
if the central atom has 6 electron pairs with 1 lone pair `
the shape is square pyramidal
if the central atom has 6 electron pairs with 2 lone pairs
the shape is square planar
combined gas law
P1V1 = P2V2
——– ———
T1 T2
R gas constant
.0821 atm / mol K
Dalton’s Law
P total = Pa + Pb + Pc
Partial Pressure
Pa = (Ptotal) (Xa)
Partial Pressure Pt. 2
total moles of gas
volume derviation
V= m
—-
D
density derivation
D = Pm
——
nRT
density derivation with MM (molar mass)
D = P (MM)
———–
RT
molar mass derivation
MM = DRT
——–
P
speed of light
2.98 E8
planck’s constant
6.626 E34
Avogadro’s number
6.022 E23
Energy and electromagnetic radiation
E=hv
E= energy change h= planks v= FREQUENCY
frequency and wavelength
c = ^v
c= speed of light ^= wavelength in METERS v= wavlength
Beer’s law
A = abc
A= absorbance b= path length a= molar absorptivity c= concentration in molarity
A= log (I0/I)
I0: incident intensity
I: transmitted intensity
KINETIC ENERGY AND TEMPERATURE
ek = (3/2) x (R/Na) x T
Na: Avagadros Number
R: Gas constant
T: Temp in K
GRAHAMS LAW
v2 = square root OF (3RT)
——
(M)