Vecka 3 Flashcards
Describe the principle of TSAAD and explain advantages compared to anaerobic degradation in a typical landfill containing organic waste.
TSAAD - Two-Step AnAerobic Degradation
The method is not used that much.
Step 1: food waste turns acid, high organic concentrations. Step 2: waste that is already in methanogenic state, are happy to have degradable material, produces gas. Metals are trapped in this step.
The leachate is strong and then goes to the second step and produce gas.
Advantages: The leachate will turn into gas instead of going into leachate treatment. Metals are trapped in the second step, and therefore it is not as much in the leachate going out.
Possible advantages of TSAAD over conventional landfilling were summarised by Lagerkvist as:
- No or minimal methane emission from the landfill to the atmosphere during acidogenic degradation.
- Formation of methane can be controlled – both with regard to where and when it should be formed. In addition, the production rate can be varied when desired.
- Many hazardous compounds are mobilised during the acidogenic conditions and are degraded or fixed during methanogenic conditions. This makes it possible to liberate large waste volume from a share of its most harmful constituents and to concentrate these in a smaller volume.
The waste is placed in a cell where intense acidogenic conditions are promoted, chiefly through moisture addition and the minimisation of air contact. The development of a methanogenic microflora is under these conditions suppressed by a low pH and high volatile acid concentration. In parallel, a volume stable methanogenic conditions is established. Because the main substrate of MSW cell is used as the second step, a reasonable volume may be about 1/!0 of the acidogenic cell. Another alternative is to use high-rate reactors for the methanogenic step, in which case further volume reduction is possible
Briefly describe the different degradation phases occuring in a landfill containing biodegradable waste.
Acidogenic and methanogenic.
Aerobic and anaerobic degradation.
The biological degradation starts already before the waste is collected and it continues in the landfill. To begin with aerobic degradation processes will dominate, but when the oxygen brought into the landfill with the waste has been consumed, anaerobic degradation processes will dominate. Anaerobic degradation proceeds in several steps.
- Hydrolysis: Large organic molecules are converted into smaller, soluble molecules such as short chain fatty acids, simple sugars and amino acids.
- Acidogenesis: The hydrolysed compounds are converted by bacteria into organic acids and alcohols. These are further degraded to smaller compounds. As a result, the pH decreases. The gas formed in this stage contains mainly CO¬2 and little H2.
- Methanogenesis: Organic acids, formed in the acidogenic stage, are converted into CH4 and CO2. An important intermediate as acetate since methanogens can only consume 1- and 2-C-compounds. Methane generation may start within a few months but may also take several years. Methanogens are more sensitive to sudden changes in their environment than the acidogens, e.g., oxygen may poison methanogens.
The aerobic, acidogenic and methanogenic degradation states are three characterstic degradation states of landfilled organic waste that are controlled by biological degradation processes. How do they affect leachate quantity and quality?
Leachate quantity and quality lecture, graphs with the different states and the composition of gas, leachate etc.
COD is higher in acid phase and than decreases in the transition phase to stable methane phase.
pH increases where the highest pH is in the end of acid phase and than decreases in the stable methane phase.
NH4+ increases and has a peak in the acid phase but then is quite stable in the transition phase with a slow decrease to the methane phase.
SO42- is high in the aerobic phase, than increases to the peak in the acid phase. It then “drastically” decreases in the transition phase, hitting “bottom” and then doesn’t really exist in the methane phase.
Cl has a steady decrease from the beginning to the end.
HCO3- increases from the acid phase to the methane phase were it is the highest.
Zn, Fe has it’s highest peaks in the acid phase to then decrease in the transition phase to be “non existent” in the methane phase.
From examination questions and example answers:
- Aerobic phase: high degradation rate leads to compaction and high temperatures lead to drought, thus some leachate will be pressed out of the material, but in small amounts with high concentrations.
- Acidogenic phase: high organic content (BOD, COD, BOD/COD >0.4), low pH and alkalinity, high concentrations of most metals. Leachate volumes are reduced slightly by hydrolysis but are much higher than during aerobic degradation.
- Methanogenic phase: low organic content (BOD, COD, BOD/COD <0.2), immobilization of metals in the waste matrix,… water loss in gas yields similar leachate volumes as during acidogenic degradation.
Discuss advantages of using ratios of variables e.g., BOD/COD, N/P, CH4/CO2 compared to using each variable separetly. When would you use what (ratio or single)?
BOD/COD, indicates the percentage of organic matter that is biologically degradable.
N/P, changes with degradation state since the mobilisation of P is much lower under methanogenic conditions than in acidogenic. E.g., in experiments where the biodegradable fraction of MSW was treated acidogenically and methanogenically, the ratios were 5 and 0.14 respectively.
CH4/CO2, expresses the methane content of the biogas. This indicates what types of substrate the gas is generated from, or may indicate the type of biological process in which the gas has been generated or converted (CH4/(CH4+CO2).
Single: if you want to know the concentration
You are responsible for the operations of a landfill receiving large amounts of easilty degradable organic material. If you want to avoid the acidogenic degradation phase, what strategy can be used to achieve this?
Leachate quantity and quality, slide with the 0.5 compost layer
Pre-treated layer in the bottom takes care of the nasty leachate and produces gas instead.
Pre-treated, but no place or so. What can you do in the landfill? Fråga Amorina vad hon svarade. Put a compost in the bottom, it takes care of the leachate from the “new” waste on top and produces methane.
Argue for separates treatment of municipal wastewater and landfill leachate.
Since the volumes of leachate from the landfill can vary throughout the year (seasonal changes etc) it is not always suitable for the leachate to go into the wastewater plant. There are also sometimes other elements in the leachate that the wastewater plant is not “used to” handle/treat, which means that some elements can go to the recipient when it shouldn’t. Also, one argument is that landfills are often not close to cities, which also wastewater plants are, but they are often not as close, which means that the leachate from the landfill must be pumped through pipes long distances.
From the lecture:
- Effects often poor
- Variation in flow and quality (seasonal, precipitations & irrigation events) equalisation basins
- Differences in quality: higher contents of COD, AOX, N (NH4), metals (Fe, Mn) and salts; lower amounts of P and particles; dependency on degradation phases
From examination questions and example answers:
Basic considerations for the choice of leachate treatment:
- Flexibility with regard to leachate quantity and quality
- minimization of all rest products
- Avoid to add extra substances like flocculants, precipitants
- Compliance with current and future regulations (e.g. discharge limits)
- Conformance and compatibility with secondary or extensive treatment steps
- Technical and economical feasibility
Co-treatment with municipal wastewater:
- Effects often poor; treatment in the MWW plant is not designed for (methanogenic) landfill leachate
- Variation in flow and quality (seasonal, precipitations & irrigation events). Can be solved with equalisation basins
- Differences in quality
- Higher COD, AOX, N (NH4), metals (Fe, Mn), salts
- Lower P
- Less particles
- Dependency on degradation phases (pH, concentrations, …)
Why is it important to make analyses immediately after sampling?
- Vissa bakterier Kanske trivs I miljön
- Saker kan oxidera
- Volatila substanser kan försvinna
Leachate quantity and quality “changes in redox potential, pH, and suspended solids for leachate stored in closed bottles at 5oC.
Conductivity may decrease as well as COD. The turbidity increases. The redox potential increases with time as well as the suspended solids (SS). The pH looks quite stable but with a slight increase after some time to then decrease
In what ways can nitrogen be reduced in leachates?
Three general possibilities:
1. Incorporation into the biomass (micro-organisms or higher plants) area and time extensive, season dependent
2. Oxidation of NH4+ to NO3- with subsequent reduction to N2 (N/DEN) demand of energy, reducing agent, time, area; sensitive micro-organisms (N)
3. Anammox = anaerobic ammonium oxidation, carried out by a group of planctomycete bacteria: NH4+ + NO2- - N2 + H2O
A natural treatment system consists of three active parts. Name them and briefly describe the function of each part.
Soil particles –> filtration, retention
Soil organisms –> biodegradation (C) and transformation (N)
Plants –> incorporation, filtration, carbon source, surfaces for bacteria, wind protection, O2 source below water surface due to photosynthesis etc.
What are the main pathways for carbin during aerobic and anaerobic waste degradation?
Split the landfill in the possible phases.
In aerobic degradation- CO2 is produced and water. Quite strong leachate. Main part is the gas phase.
In anaerobic degradation- Acidogenic: leachate; Methanogenic: LFG
From examination questions and example answers:
Aerobic: CO2 and biomass
Acidogenic: leachate
Methanogenic: LFG
Explain why landfills may emit material?
Not a closed system. Reactions, such as gas, dissolution (rainwater gets polluted), diffusion.
If it is not mechanically stable, landslides can happen.
From examination questions and example answers:
There are several drivers of landfill emissions, some of the more important are
- Concentration gradients between the landfill and its surroundings
- Reactivity if the waste – chemical energy within the material, which can power reactions and phase changes.
- Fluxes of liquid or gases in the environment that may pass the landfill or part of it.
- Gradients of potential energy ca cause slides.
Why does the leaching of lead decrease when the degradation state of a landfill shift from acidogenic to methanogenic conditions?
In acidogenic conditions there is more Pb than in methanogenic conditions. This can be explained by in the acidogenic state, there is lower pH, which makes the Pb more mobile (?). If considering Pb to behave in the same way as Zn and Fe in a landfill, then there is more of the element in the acidogenic state than in the methanogenic state since there is an increase of pH when the landfill goes to methanogenic state.
From examination questions and example answers:
- The pH increases
- The pe decreases and sulphide complexes may be formed
- Organic complexing agents are degraded
The BOD/COD ratio of a leachate is often used to characterize the degradation state of a landfill:
- What do the abbrevations stand for?
- What is the relevance of a quotient in the range of 0.05-0.1 regarding the degradation processes in landfills and the consequences regarding leachate treatment?
The BOD/COD ratio can describe if the landfill is in methanogenic or acidogenic state. If it is between 0.05-0.1 it means that the landfill is in methanogenic state, which means that there is methane is increasing. What that means is that there could be less amount of dissolved metals and more particles in the leachate. The pH is higher than in the acidogenic state.
From examination questions and example answers:
- Biological/chemical oxygen demand
- Methanogenic degradation
- Basically hardly degradable organic matter, moderate-low metal content, etc –> difficult with biological treatment, poor effects if co-treatment with municipal solid waste water, etc
Name and briefly describe three decisive (important) factors for the amount of leachate that can be expected from a landfill. When in the lifetime of a landfill can you expect most leachate?
The most amount of leachate is expected in the middle of the lifetime of a landfill. This is because the waste in the water must be saturated before it could start to “leak”.
Important factors: L/S ratio, how much water comes in (leachate quality: decisive factors for leachate quantity), groundwater pressure. Technical measures, how is it covered, how is the cover designed. No liquid waste to landfills. When do have more leachate?
From examination questions and example answers:
- Climate
- Landfill geometry
- Cover materials and design
- Waste properties (humidity, permeability)
- Degradation state
- Bottom liner & collection systems
- Operation … leachate recirculation
During aerobic degradation the share of the substrate that goes into new biomass is up to about 40%, yielding a BOD/COD of 0.6. If you see a BOD/COD of 0.1, what can that mean?
Aerobic biodegradability cannot be larger than 0.6, because aerobic degradation has a 40% cell yield.
Low ratio, hard to degrade substrate.
It could also be a nice degradation but there is something hindering the degradation process, it could be toxins and chemicals (affects on BOD). COD in the lab, strong oxidising agent, so even Fe and other stuff not organic that gets oxidised.
From examination questions and example answers:
- The organic material is not readily biologically degradable, but oxidizable
- There are non-organic components in the material, which consume chemical oxidant
- Something is affecting the BOD-assay, e.g. toxicity