Vapour Flashcards
Define systems and surroundings
- Surroundings are the whole universe
- The system is part of the universe which contains a definite quantity of matter and is confined within some closed surfaces
Define Controll volume
space into which, or from which, a substance flows
Define an intensive property
does not depend on mass
Define an extensive property
depend on mass of system
Define a thermodynamic property
- qualities that serve to describe a system.
- have a unique value when a system is in a particular state and do not depend on the previous state
Define a thermo dynamic system
quaintly if mater contained within some closed surface
Define a phase
quantity of matter that has the same chemical composition throughout
Define a state
condition as described by giving values to its properties at particular instants
What is a process?
path of successive states through which a system passes
How do you work out the change in property?
integral of d phi between phi 2 and phi 1 = phi 2 - phi 1
What is the quality of a liquid-vapour system
ratio of mass of saturated vapour to total mass in the system
What is the equation for quality
x = mg / m
What does first law state?
during any cycle that a system undergoes, the cyclic integral of the heat quals to the cyclic integral of the work
Draw a TV graph and state its regions
- R4
- superheated
- quality
- compressibility
What is the alternative form of first law?
Q(1-2) = E2 - E1 + W(1-2) dE = delta Q - delta W
What does the total heat transfer equal?
Q = u2- u1 +m(v2^2 - v1^2)/2 + mg (z2-z1) + w2
What does enthalpy equal for steam?
h = (1-x)hf + xhg
What does enthalpy equal for other gases?
h = cpT
What does the volume of steam equal?
V = m (xvc + (1-x)vf)
For constant volume and specific heat, what does the change in internal energy equal?
u2 - u1 = integral of Cv dt between T2 nd T 1
For constant pressure and specific heat, what does the change in enthalpy equal?
h2 - h1 = integral of cp dt between T2 nd T 1
From first law what does h1 equal?
H1 = H2
What does the heat transfer out equal?
Q out = hin - hout
What are the relations for a isobaric process?
P1 = P2 = V1/T1 = V2/T2 Q = mCv(T2 - T1)
What are the relations for an isothermal process?
T1 = T2 = P1 V1 = P2 V2
Q = mCp(T2 - T1)
Q - W = delta U
What are the relations for an adiabatic process?
P1V1 ^ y = P2V2 ^ y
change in U = (P2V2 - P1V1)/(1 - k)
T2/T1 = (V1/V2)^k-1
T2/T1 = (P2/P1) ^k-1/k
What is an adiabatic process?
occurs without transfer of heat or matter
What are the relations for a poly tropic process?
P1V1^n = P2V2^n
What does the mass flow rate equal?
row 1 A 1 V 1 = m1 = m2 for a steady state
What are pumps?
- devices that transfer energy to a gas flowing through them
- increase pressure
What are compressors and blowers?
- transfer energy to a gas flowing through them
- increase pressure
What are turbines?
- work is down by a fluid on a set of rotating blades
- pressure decreases
What is a nozzle?
-increase velocity for a flowing fluid by decreasing pressure
What is a diffuser?
-increase pressure by decreasing velocity
What is the equation for net work on a compressor/turbine/pump?
W = m (h2 - h1)
What is a heat exchanger?
devices that transfer heat from hotter body to colder body or to surroundings
What are the features of heat exchangers?
- velocity doesn’t change
- pressure drop is small
- protenial energy change is negligible
- no work occurs
What is the heat transfer equation for heat exchangers?
Q = m (h2 - h1)
What does the second law state?
Processes proceed in certain directions
What is a heat engine?
device that operates in a thermodynamic cycle and does a certain amount of net positive work through the transfer of heat from a high temperature body to a low temperature body
What is a heat pump?
device that operates in a cycle that requires work and that accomplishes the transfer of heat from a low T body to a high T body
What is the thermal efficiency of a heat engine?
n = W/Qh = 1 - Ql/Qh
What is the efficiency of a heat pump?
B = Ql/ W = Ql/(Qh-Ql)
What is the kelvin - plank statement?
It is impossible to construct a heat engine that operates in a cycle that receives a given amount of heat and does an equal amount of work
What is clausis statement?
It is impossible to construct a refrigerator that operates without input of work. This implies that coefficient of performance b is less than infinity
What is a reversible process?
a process that once having occurred can reverse and in doing so leave in changes in either system of surroundings
Why is a carnot cycle the most efficient?
every process is reversible
What are the four stages in a carnot cycle?
1) revisable isothermal expansion
2) reversible adiabatic expansion
3) reversible isothermal compression
4) reversible adiabatic compassion
For all revisable heat engines what is Q equal to?
integral of delta Q/ T = 0
For all irreversible heat engines what is Q equal to?
integral of delt Q/T less than 0
What is entropy?
unavailability of a system’s thermal energy for conversion into mechanical work, often interpreted as the degree of disorder or randomness in the system.
What is the change in entropy?
s2 - s1 = integral of delta Q / T
In a saturated region, what is the entropy?
s = sf + xsfg
What is the change in entropy of ideal gasses?
s2 - s1 = cv ln(T2/T1) + k ln(v2/v1)
What does T ds equal?
T ds = dH - Vdp
= du + Pdv
What is the efficiency of a turbine?
Wa/Ws
What is the efficiency of a compressor?
Ws/Wa
What are the 4 processes in a ranking cycle?
1-2 isentropic compression (pump)
2-3 constant pressure heat addition (boiler)
3-4 isentropic Expansion (turbine
4-1 contrant pressure heat extraction
What is the efficiency of a rankine cycle?
n = Wt/Qb
How can you improve a rankine cycle?
- increase output pressure P2 or boiler outlet temp T3
- increase boiler pressure while maintain T mad and min P
- however this does lead to low quality of steam and the droplets cause damage to turbines
What is the rankine reheat cycle
- steam passing through turbine is reheated which raises T to state 5
- steam then passes through low P section of the turbine and enters condenser at state 6
- this then reduces moisture in the turbine
What is the coefficient of performance for the vapour refrigeration cycle
COP = B = Q in / W in
Why isn’t an actual vapour refrigeration cycle ideal
- pressure drops due to friction in pipes
- heat transfer through pipes
- pressure drops and heat transfer in condenser
- fictional effects