Vapour Flashcards
Define systems and surroundings
- Surroundings are the whole universe
- The system is part of the universe which contains a definite quantity of matter and is confined within some closed surfaces
Define Controll volume
space into which, or from which, a substance flows
Define an intensive property
does not depend on mass
Define an extensive property
depend on mass of system
Define a thermodynamic property
- qualities that serve to describe a system.
- have a unique value when a system is in a particular state and do not depend on the previous state
Define a thermo dynamic system
quaintly if mater contained within some closed surface
Define a phase
quantity of matter that has the same chemical composition throughout
Define a state
condition as described by giving values to its properties at particular instants
What is a process?
path of successive states through which a system passes
How do you work out the change in property?
integral of d phi between phi 2 and phi 1 = phi 2 - phi 1
What is the quality of a liquid-vapour system
ratio of mass of saturated vapour to total mass in the system
What is the equation for quality
x = mg / m
What does first law state?
during any cycle that a system undergoes, the cyclic integral of the heat quals to the cyclic integral of the work
Draw a TV graph and state its regions
- R4
- superheated
- quality
- compressibility
What is the alternative form of first law?
Q(1-2) = E2 - E1 + W(1-2) dE = delta Q - delta W
What does the total heat transfer equal?
Q = u2- u1 +m(v2^2 - v1^2)/2 + mg (z2-z1) + w2
What does enthalpy equal for steam?
h = (1-x)hf + xhg
What does enthalpy equal for other gases?
h = cpT
What does the volume of steam equal?
V = m (xvc + (1-x)vf)
For constant volume and specific heat, what does the change in internal energy equal?
u2 - u1 = integral of Cv dt between T2 nd T 1
For constant pressure and specific heat, what does the change in enthalpy equal?
h2 - h1 = integral of cp dt between T2 nd T 1
From first law what does h1 equal?
H1 = H2
What does the heat transfer out equal?
Q out = hin - hout
What are the relations for a isobaric process?
P1 = P2 = V1/T1 = V2/T2 Q = mCv(T2 - T1)
What are the relations for an isothermal process?
T1 = T2 = P1 V1 = P2 V2
Q = mCp(T2 - T1)
Q - W = delta U