uranium in the earth 5&6 Flashcards
sun can only form elements up too
iron -56
enriched continental crust
1.4ppm of U
U, K and Th are large ‘lithophile’ elements and do not readily fit into the structures of the main High-T forming
minerals
*During magma fractionation in the crust, U, K and Th are partitionned into the increasingly small volume
of residual melt
mantle has much less uranium than primitive
earth energy source
radioactive decay of uranium and thorium and potassium -drives mantel convection- decreasing source
heat released during progressive solidification of the core
why U enriched in crust
dig atom, doesn’t fit in crystal structure
every time there is partial melt in the mantle U kicked out so it carried to the surface
shift from methan to oxygen
reducing to oxidising atmos
U in oxidised for is soluble
can reprecipitate in different locations
in situ leach
less energy extensive
more envio friendly
injecting highly acid fluid from a input to an output borehole -dissolves out the valuable metals
worker less exposure
uranium resource
can extract it from seawater -expensive
70yr of fuel guaranteed deposits
U+6
mobile
oxidised
sometime forms uranyl
why doesn’t U fit into structures
lots of electrons
ionically huge
U mineralogy
chemically reduced forming…
pitchblende -black, dense, reduced U+4
U mineralogy
Ionic radius of U, means it can
substitute for other metals in
silicate and oxide structure
zircon use
used for mineral dating
same structure as coffinite (ZrSiO4)
uranium 6 (normally bonds to what first)
double bonds to oxygen so it has one either side of it
thermodynamic, strong, stable
uranium 6 minerals colour
bright yellow or green
some glow in the dark due to
the urinal bond (U6) inside- takes in UV light and expresses it back out)