Unit 8 – Acid-base Titration Flashcards

1
Q

It is a method of quantitative analysis for determining the concentration of an acid/base by neutralizing it with standard solution of base/acid.

A

Acid-base Titration

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2
Q

Types of acid-base titration

A

Alkalimetry
Acidimetry

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3
Q

It is the determination of BASIC CONTENT in a sample by titrating it with a standard acid solution.

A

Alkalimetry

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4
Q

It is the determination of ACID CONTENT in a sample by titrating it with a standard acid solution.

A

Acidimetry

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5
Q

T/F
In ALKALIMETRY, the BASIC CONTENT should be titrate with ACID.

A

T

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6
Q

T/F
In ACIDIMETRY, the ACID CONTENT should be titrate with a standard BASIC solution.

A

T

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7
Q

It is the course of an acid-base titration that is best followed by examining the pH as the titration progresses.

A

Titration Curve

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8
Q

It provides a visual picture of how the property of the titration reaction changes as the titrant is added to the analyte.

A

Titration Curve

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9
Q

Stages in the titration

A

Pre-equivalence point
Equivalence point – end point
Post-equivalence point

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10
Q

Equivalence points in acid-base titrations are determined most often using _____ that change color at or near equivalence point.

A

Chemical indicators

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11
Q

_____ are WEAK ORGANIC acids or bases whose conjugate forms have different colors.

A

Acid-base indicators

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12
Q

T/F
It must be WEAKER than the ANALYTE acid or base that it reacts last with the titrant.

A

T

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13
Q

An average observer visualizes color imparted by a typical indicator within concentration ratio: _____

A

[Hin] / [In-] = 10 to 0.1

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14
Q

It is the point in titration having the GREATEST SLOPE.

A

Inflection point

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15
Q

It very nearly coincides with the equivalence point.

A

Inflection point

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16
Q

T/F
To MINIMIZE titration error, an indicator’s entire transition pH range must fall WITHIN the rapid change in pH at the equivalence point.

17
Q

This is the use of strong acids or strong bases.

A

Standard solution (titrant)

18
Q

This react more completely with an analyte, yielding a sharper endpoint.

A

Standard solution (titrant)

19
Q

It is widely used for titration of bases

20
Q

It is a strong acid and dilute solutions are stable with little or reducing power.

21
Q

T/F
Chloride ions does not form precipitates with most cations.

22
Q

It is a concentrated acid and NOT a PRIMARY STANDARD.

23
Q

It forms insoluble sulfates with a number of common cations.

A

Sulfuric acid

24
Q

Standard bases used for standardization of acids.

A

Primary standard bases

25
It is most often used for standardization of acid solutions.
Primary standard bases
26
Most often used for the standardization of acid solutions.
Sodium carbonate
27
High purity solid that are commercially available, but is hygroscopic.
Sodium carbonate
28
It is also known as borax.
Sodium tetraborate
29
T/F Sodium tetraborate cannot be heated to remove water.
T
30
Sodium tetraborate is stored in dessicator over an aqueous solution saturated with _____ and _____.
NaCl and Sucrose
31
It is used almost exclusively for titrating acids in solutions.
NaOH
32
T/F Dilute NaOH solutions are stable and can be stored in plastic containers.
T
33
It slowly reacts with glass to form soluble silicates.
NaOH
34
It has a cementing property; often glass stoppers are "freeze" tightly to the mouth of the container.
NaOH
35
T/F NaOH must be protected from oxygen.
F. It should be protected from carbon dioxide/