Unit 3: Chapter 6 - Acids and Bases Flashcards
Empirical Properties of Strong Bases
Very high pH»_space;7
High conductivity
Fast reaction rate
Empirical Properties of Weak Bases
Medium to high pH >7
Low conductivity (only if molecular)
Slow reaction rate
Modified Arrhenius Theory: Strong Acids
Completely react with water to form aqueous H3O+ ions (100%)
Modified Arrhenius Theory: Weak Acids
Partially react with water to form H3O+ ions (50%)
Modified Arrhenius Theory: Strong Bases
Completely dissociate to form OH- ions (100%)
Modified Arrhenius Theory: Weak Bases
Partially react with water to form OH- ions (50%)
Define: Monoprotic Acids
Acid with only one hydrogen atom and only react once to produce H3O+ ions
Define: Polyprotic Acids
Acids that contain more than one acidic hydrogen and react more than once with water to form H3O+ ions
Exemption to Polyprotic Acid Rule
Sulfuric Acid - Because the first reaction with water is essentially complete and the second is 50%
Modified Arrhenius Theory: Acids
Substance that react with water to produce hydronium ions
Modified Arrhenius Theory: Bases
Substance that react with water to produce hydroxide ions
Modified Arrhenius Theory: Neutralization
The reaction between hydronium and hydroxide to produce water
What’s the relationship between the pH and pOH and the ion concentration?
Inverse relationship
The higher hydronium ion concentration , the lower the pH
pH and pOH sig dig rule
Digits following the decimal point = sig digs
Hydronium concentration for neutral solution at SATP
1x10 -7 mol/L
Hydronium concentration for acidic solution
> 1x10 -7 mol/L
Arrhenius’ Theory: Acids
Acids ionize with water to produce a hydrogen ion and an anion
Arrhenius’ Theory: Bases
Bases are soluble ionic compounds that dissociate into a cation and a hydroxide ion
pH Formulas
pH = -log [H3O+(aq)]
[H3O+(aq)] = 10 -pH
pOH Formulas
pOH = -log [OH- (aq)]
[OH- (aq)] = 10 - pOH
What’s an acid-base indicator?
Substances that change colour when the acidity of the solution changes
Lower pH form of Indicator
HIn (aq)
High pH form of Indicator
In- (aq)
Empirical Properties of Weak Acids
Medium to low pH
Empirical Properties of Acids In General
Taste sour
Turn blue litmus red
Have pH
Empirical Properties of Bases in General
Taste bitter Feel slippery Turn red litmus blue Have pH >7 Neutralize acids
General Polyprotic Acid and Base Rule
Polyprotic bases and acids are weak, as each reaction with water causes their strength to decrease with each successive step
Define: Amphiprotic
A substance that can become either an acid or a base (usually containing a negatively charged ion starting with H)