Unit 3 Flashcards

1
Q

Electromagnetic Spectrum

A

the full range of electromagnetic radiation, organized by frequency or wavelength

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2
Q

En (total energy of nth state)

A

En= (-2.18 x 10^-18 J)(z^2/n^2)
or
En= (-13.6 eV)z^2/n^2)

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3
Q

Z

A

atomic number, the charge number of an atomic nucleus

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4
Q

eV (electric volt)

A

1.602 x 10^-19 J

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5
Q

a0

A

a0= 52.9 pm
Bohr radius (the most probable distance between the nucleus of a hydrogen atom and its single electron when the atom is in its ground state (lowest energy level))

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5
Q

pm

A

1 x 10^-12 m

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5
Q

rn

A

-rn= (n^2/z) x a0
-radius of orbit of electron when atom is in nth state

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6
Q

spectrum of incoming light

A

the distribution of different wavelengths of light (colors) that are hitting a substance

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7
Q

distinct energy

A

the concept that electrons in an atom can only occupy specific, fixed energy levels, meaning they can only have certain distinct values of energy, not a continuous range of energies

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8
Q

line in spectrum

A

each line represents a unique λ

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9
Q

spectrum of elements

A

each element has a unique spectrum

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10
Q

Bohr’s model of the atom

A

-atoms exist in discrete or quantized states
-these energy states are described by a quantum number (n=1, 2, 3,…)
-atom transitions between energy states in quantum leaps
-energy is conserved, the energy of the quantum leap is the energy of the photon emitted or absorbed by the atom
-Bohr’s energy equation is applied to one electron atoms/ions
-total energies of bound states are negative and conserved

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11
Q

quantum leap

A

a huge, often sudden, increase or advance in something

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12
Q

emission

A

-Eph= -∆E(atom)
-atom loses energy
-atom becomes more stable

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13
Q

absorption

A

-Eph=∆E(atom)
-atom (ion) gains energy
-atom becomes less stable

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14
Q

binding energy

A

the amount of energy needed to completely remove an electron from its orbit around the nucleus

15
Q

first excited state

A

On the energy level diagram of a system, the state immediately above the ground state

16
Q

ground state

A

The state of lowest energy for an atom, molecule, or collection of molecules

17
Q

Å (angstrom)

A

1 x 10^-10 m

18
Q

bound system

A
  • -E(tot)
    -a collection of atoms or molecules held together by attractive forces, where the total energy of the system is negative