UNIT 2 Titration and Normality Flashcards
What is the use of titrations?
determine the quantity of reagent f known concentration that is required to react completely with an analyte
What is needed to be know for a titration?
Concentration of reagent –> standard solution
What is equilibrium?
When the reagents have reacted completely with analytes
–> need an indicator to know when that has happened
Equivalence point
Equal amounts has been sonsumed between the titrant and analyte
Overshoot
Add extra volume–> extra moles and notaccurate
End point
Physical chaneg has occured associated
Titration error
Et=V(endopint)-V(eq point)
What is a primary standard?
Ultrapure chemical compounds that is used fro reliability of titration
What is a secondary solution?
compound whose purity has been determined by chemical analysis
How do you make a secondary solution?
Titrated with primary standard in order to determine exact concentration and make it a standard
What is back titration?
Adding excess of standard solution to consume an analyte is determined by titration with a second standard solution
What is an example of back titration?
Iodine Value:
- iodine saturates the double bond
- determine the amount of O2 that saturated the double bond
- add excess and titrate what is left –> find moles that is not consumed
What is normaility?
Expresses solution concentration
Number of equivalents contained in 1L of solution
What is the indicator?
Added to analyte solution to produce observable signaling of the endpoint
What is Gravimetric titration?
Mass of titrant s measured rather than the volume