Unit 2 Flashcards
What is a homologous series?
A homologous series is a group of chemicals which;
- Have the same general formula
- Similar chemical properties
- A gradual change in physical properties
What are the 3 main homologous series ‘groups’?
Alkenes
Alkanes
Cycloalkanes
What is the general formula for the Alkanes?
Cn+H2n+2
What are the prefixes for the homologous series?
1) Meth-
2) Eth-
3) Prop-
4) But-
5) Pent-
6) Hex-
7) Hept-
8) Oct-
9) Non-
10) Dec-
What are the 2 structures?
Straight chain and Branched
What is an Isomer?
Isomers are molecules with the same chemical formula but different structural formula.
They have the same number of each type of atom but may have different physical and chemical properties.
What are the rules for systematic naming?
- Identify the longest chain of carbons.
- Number the carbon so that the branches (if any) are on the smallest number of carbon possible.
- Any carbons which aren’t in the longest chain are part of a branch. Branches should have their name and position on the longest chain of carbons. These branches have the suffix -yl.
- Then put the name together, for example;
2-methylpentane
‘2’ being the position of the branch and methyl being a branch of 1 carbon.
Note: If you are systematically naming an alkene or alcohol you would put the position of the double bond (alkene) or the position of the hydroxl functional group.
What is the general formula for the alkenes?
CnH2n
What is a hydrocarbon?
A hydrocarbon is a compound which only contains Hydrogen and carbon.
What is the general formula for the cycloalkanes?
CnH2n (the same as the alkenes)
What is the first member of the alkenes?
Ethene
How do you test for unsaturation?
To test for unsaturation, a chemical can be shaken with bromine solution (bromine water). The bromine solution (bromine water) will be decolourised immediately if a chemical is unsaturated.
Which homologous series member is unsaturated?
The Alkenes
What type of bonds do the cycloalkanes and alkanes have?
Only single carbon to carbon bonds (C-C)
What is a addition reaction?
A reaction in which one molecule combines with another to form a larger molecule with no other products.
How does an alkene form an alkane?
It’s possible to make alkane molecules from alkenes by carrying out an addition reaction known as hydrogenation, (an addition reaction including hydrogen/ H-H).
What is cracking?
Cracking is a process when large molecules are broken up into smaller more useful ones. This process is usually carried out with the use of a catalyst, usually aluminium oxide, which allows the process to be carried out at a lower temperature.
What are the products of cracking?
A smaller chain alkane and at least one smaller chain alkene is formed.
Give an example of when cracking is useful:
It’s particularly useful when the fractional distillation of crude oil produces a high quantity of a large fraction which is not heavily in demand.
What are alkenes commonly used for?
They’re commonly used to make polymers (plastics) and to make alcohols.
Are alkenes soluble is water?
No